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Start Over Descriptor "decoy molecule" Journal angewandte chemie international edition
1 results on '"decoy molecule"'

1. Highly Selective Hydroxylation of Benzene to Phenol by Wild-type Cytochrome P450BM3 Assisted by Decoy Molecules.

Author

Shoji, Osami, Kunimatsu, Tatsuya, Kawakami, Norifumi, and Watanabe, Yoshihito

Subjects
*BENZENE synthesis, *PHENOLS, *MONOOXYGENASES, *HYDROXYLATION, *ENZYMES
Abstract

Playing tricks on enzymes: Direct hydroxylation of benzene to phenol was catalyzed by wild‐type P450BM3 in the presence of perfluorinated carboxylic acids as decoy molecules. The catalytic turnover rate reached 120 min−1 per P450. The selectivity towards phenol production was very high and no overoxidation products were detected. [ABSTRACT FROM AUTHOR]

Published
2013
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