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Start Over Author "Mutus, Joshua Y." Journal angewandte chemie. international edition
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2. The Extended Borinium Cation: [(tBu3PN)2B]+

Author

Courtenay, Silke, Mutus, Joshua Y., Schurko, Robert W., and Stephan, Douglas W.

Abstract

A linear arrangement of the P‐N‐B‐N‐P linkageoccurs in the unique extended structure of the cation of the borinium salt 1, which was obtained from the reaction of [tBu3PN]Li with BCl3. The related species (tBu3PN)2BH was also prepared and shown to react with [Ph3C][B(C6F5)4] to afford the analogous salt [(tBu3PN)2B][B(C6F5)4]. NMR data and ab initio computations infer that tight ion pairing occurs for 1in nonpolar solvents.

Published
2002
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