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In this study, based on the characteristic of lanthanide in oxygen storage capacity, a series of Pr a Ti b O x composite supports with different mole ratios of Pr to Ti and the corresponding Au catalysts were prepared - to investigate the oxidation of CO under CO 2 -rich atmosphere with lean oxygen content. A significant promotion in CO conversion rate over the catalyst with a molar ratio of Pr:Ti = 1:2 and a very high catalytic stability was also obtained. The addition of optimal Pr will make smaller gold particles, provide higher capacity in surface reactive oxygen releasing at low temperatures and weaken the deposition of carbonates in CO 2 -rich atmosphere. However, more Pr will strongly interact with gold, which leads to the majority of Au+ species in the catalysts and thus lower the catalytic activity. This study may provide a potential application of rare earth elements in sealed CO 2 -laser. [Display omitted] • The Pr a Ti b O x composites supported Au catalysts were studied for CO oxidation with CO 2 -rich feed. • The optimal catalyst was found with a molar ratio of Pr:Ti = 1:2. • Good catalytic performance correlated to the easy surface reactive oxygen releasing and weak deposition of carbonates. • The majority of Au+ species in the catalysts with higher Pr content results in worse performance. [ABSTRACT FROM AUTHOR]