1. Development of AEI-type boroaluminosilicate zeolites, and their acidic and catalytic properties in ethene conversion reaction
- Author
-
Masato Yoshioka, Junko N. Kondo, Toshiyuki Yokoi, and Yusuke Kunitake
- Subjects
Chemistry ,Process Chemistry and Technology ,Inorganic chemistry ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Catalysis ,0104 chemical sciences ,law.invention ,Boric acid ,chemistry.chemical_compound ,Solid-state nuclear magnetic resonance ,law ,Aluminosilicate ,Molecule ,Calcination ,0210 nano-technology ,Selectivity ,Zeolite - Abstract
Incorporation of B atoms into the AEI-type framework was successfully achieved by addition of boric acid into the starting gel. The gel compositions, the Si/Al and Si/B ratio, and the calcination conditions were extensively investigated to tune acidic properties of the AEI-type zeolite. The incorporation of B into the framework was confirmed by solid state NMR and FT-IR techniques. In-situ FT-IR spectroscopy using CO as a probe molecule was applied to the evaluation of the acidic property. As the result of in-situ FT-IR measurement, thus obtained AEI-type boroaluminosilicate zeolites showed weak acidic properties derived from framework B species compared to the aluminosilicate one. Finally, the catalytic properties of the synthesized AEI-type zeolites in the ethene conversion reaction were investigated. We found that the AEI-type boroaluminosilicate catalyst showed a long catalytic life and a high selectivity to butenes.
- Published
- 2018
- Full Text
- View/download PDF