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Latent heat thermal energy storage is an attractive technique as it can provide higher energy storage density than conventional heat energy storage systems and has the capability to store heat of fusion at a constant (or a near constant) temperature corresponding to the phase transition temperature of the phase change material (PCM). This paper provides a state-of-the-art review on phase change materials (PCMs) and their applications for heating, cooling and electricity generation according to their working temperature ranges from (−20 °C to +200 °C). Four working temperature ranges are considered in this review: (1) the low temperature range from (−20 °C to +5 °C) where the PCMs are typically used for domestic and commercial refrigeration; (2) the medium low temperature range from (+5 °C to +40 °C) where the PCMs are typically applied for heating and cooling applications in buildings; (3) the medium temperature range for solar based heating, hot water and electronic applications from (+40 °C to +80 °C); and (4) the high temperature range from (+80 °C to +200 °C) for absorption cooling, waste heat recovery and electricity generation. Different types of phase change materials applied to each temperature range are reviewed and discussed, in terms of the performance, heat transfer enhancement technique, environmental impact and economic analysis. The review shows that, energy saving of up to 12% can be achieved and a reduction of cooling load of up to 80% can be obtained by PCMs in the low to medium–low temperature range. PCM storage for heating applications can improve operation efficiency from 26% to 66%, depending on specific applications. Solar thermal direct steam generation (DSG) is the most common electricity generation application coupled with PCM storage systems in the high temperature range, due to the capability of PCMs to store and deliver energy at a given constant temperature. The recommendations for future research are also presented which provide insights about where the current research is heading and highlights the challenges that remain to be resolved. [ABSTRACT FROM AUTHOR]

Abstract: Thermal energy storage (TES) has shown potential in improving the overall performance in energy systems, through shifting of thermal load demand, and through matching of uneven energy availability in time and in space. Latent heat TESs demonstrate advantages over sensible heat TESs for their high storage density and small temperature swing; however, lack of accurate knowledge in novel material properties and lack in a holistic design protocol often lead to difficulties in reaching technically viable storage design. With the aim of proposing a sound latent heat based TES design-to-validation protocol, this paper covers material property characterization through Temperature-history (T-history) method, heat exchanger design through heat transfer modeling, and model validation through experimental verification. A model for submerged cylindrically finned heat exchanger latent heat storage unit with phase change material was built. The results show that performance of gelled salt-hydrate based TES can be assessed with a pure conduction based model. This material property characterization-to-model verification approach may serve as a standard in providing accurate storage design for performance evaluation. [Copyright &y& Elsevier]

Abstract: The paper presents an analysis of thermodynamic losses in thermal reservoirs due to irreversible heat transfer and frictional effects. The focus is upon applications to large-scale electricity storage for which it is the loss in availability (or exergy) that is most relevant. Accordingly, results are presented as loss coefficients which are defined as the fractional loss of the entering availability. Only losses stemming from irreversibility are considered – heat losses to the surroundings are not included in the analysis. A number of simplifying assumptions have been adopted, but the results nonetheless clearly demonstrate the dependence of the losses on operating temperatures, reservoir geometry and mode of operation, and point the way towards methods of optimisation. Estimates for a typical installation suggest that the losses are not insignificant, particularly for one-off charge and discharge (i.e., for long-term storage), but remain acceptable for cyclic operation, so as to make the use of thermal reservoirs attractive for electricity storage schemes. [Copyright &y& Elsevier]

Abstract: In the paper, two systems for solar thermal power plants (STPPs) are devised for improving the overall performance of the plant. Each one attempts to reduce losses coming from two respective sources. The systems are simulated and compared to a reference STPP. They consists on: (a) a double thermal energy storage (DTS) with different functionalities for each storage and (b) the subdivision of the solar collector field (SSF) into specialised sectors, so that each sector is designed to meet a thermal requirement, usually through an intermediate heat exchanger. This subdivision reduces the losses in the solar field by means of a decrease of the temperature of the heat transfer fluid (HTF). Double thermal energy storage is intended for keeping the plant working at nominal level for many hours a day, including post-sunset hours. One of the storages gathers a fluid which is heated up to temperatures above the nominal one. In order to make it work, the solar field must be able to overheat the fluid at peak hours. The second storage is the classical one. The combination of both allows the manager of the plant to keep the nominal of the plant for longer periods than in the case of classical thermal energy storage. To the authors’ knowledge, it is the first time that both configurations are presented and simulated for the case of parabolic through STPP with HTF technology. The results show that, if compared to the reference STPP, both configurations may raise the annual electricity generation (up to 1.7% for the DTS case and 3.9% for the SSF case). [Copyright &y& Elsevier]