1. Preparation of Sc2Mo3O12 and Characterization of its Negative Thermal Expansion Property
- Author
-
Jun Li, Xiao Nong Cheng, and Jun Jun Zhu
- Subjects
Materials science ,Negative thermal expansion ,Scanning electron microscope ,Phase (matter) ,Analytical chemistry ,Thermomechanical analysis ,Thermal stability ,General Medicine ,Thermal analysis ,Thermal expansion ,Bar (unit) - Abstract
Negative thermal expansion (NTE) material Sc2Mo3O12 was prepared by solid-state method. The phase structure, morphology and the thermal stability of the obtained products were examined by powder X-ray diffraction (XRD), scanning electron microscopy (SEM) and thermogravimetric-differential thermal analysis (TG-DSC), respectively. To study its negative thermal expansion property, two methods were utilized. One is based on the in-situ XRD results and the thermal expansion coefficient (CTE) was calculated by the cell parameters obtained at different temperatures. Another is based on the thermo-mechanical analysis (TMA) and the CTE was calculated by the length of Sc2Mo3O12 bar at different temperatures. The differences between these two methods were also discussed.
- Published
- 2013
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