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Photocatalytic degradation kinetics of methylene blue in aqueous solution was systematically investigated using Ti-based composite material as the photocatalyst. The single-variable-at-a-time ( SVAT) method was employed. It studied the individual and synergistic effects of several classical parameters on photocatalytic efficiencies. The kinetic mechanism was systematically explored. The kinetics effects of the doping amount of La and N, calcination temperature and time, light intensity were studied in detail. The factors on the degradation of MB were in accordance with the pseudo first order kinetic model. This kinetic model followed the Langmuir–Hinshelwood model. The best preparation conditions were found in the experiments. It is proved that the Ti-based composite material is an effective adsorbent for the degradation of dye contaminated water.

In this work, the novel Ti-based composite material has been synthesized, characterized and studied for the photocatalytic degradation of methylene blue(MB). The effects of the doping amount of La and N, calcination temperature and time, light intensity were studied in detail. The strong synergism of La, N and TiO2 was discussed during the photocatalytic process. The results suggested that the degradation efficiency was obviously improved by the Ti-based photocatalyst and the La element could enhance the photocatalytic degradation performance significantly, and the best molar ratio of N and TiO2 was 0.000014:1. The study found that the best preparation conditions can also improve the photocatalytic activity, the optimal material was made after calcining for 4h at 800°C. What is more, the higher illumination power was benifit for the degradation of the MB. It is indicated that the mixed crystal Ti-based composite material being an effective adsorbent for the elimination of the contaminated water by dyes. In addition, the work provide new direction for future research.