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As one of the most likely alternatives to traditional vapor compression refrigeration technology, solid refrigeration technology based on the barocaloric effect (BCE) has attracted extensive attention in recent years. Spin-crossover (SCO) compounds are considered suitable for working at low driving pressures due to high-pressure sensitivity and small hysteresis width. However, the entropy change (ΔSSCO) of the SCO compound is smaller than that of other excellent barocaloric materials (plastic crystals and two-dimensional perovskites). Here, we report the BCE of the SCO compound {Fe(pz)2(BH3CN)2} (pz = pyrazine) with a smaller molar mass and a third source of entropy change besides electron and vibrational entropy changes. Compound {Fe(pz)2(BH3CN)2} exhibits high pressure sensitivity ( d T 1 / 2 d P = 20.2 K kbar−1) as well as entropy change (Δ S SCO = 202 J kg−1 K−1). The maximum values of reversible isothermal entropy change (ΔSit,rev,max) and adiabatic temperature change (ΔTad,rev,max) at 1 kbar are only 103 J kg−1 K−1 and ∼0 K, respectively, due to the hysteresis behavior. However, at sufficiently high driving pressures, ΔSit,rev,max exceeds 200 J kg−1 K−1, and ΔTad,rev,max can reach ∼47 K, which exceeds all SCO compounds reported in BCE studies and is comparable to some plastic-crystalline and two-dimensional perovskite barocaloric materials. The excellent BCE of the SCO compound {Fe(pz)2(BH3CN)2} is mainly due to its small molar mass, which makes the unit mass compound exhibit higher ΔSSCO, while the introduction of the third source of entropy change—the reorientation entropy change (ΔSreo), only plays a small role. This is expected to promote the practical application of SCO compounds as barocaloric refrigerants. [ABSTRACT FROM AUTHOR]

In a continuous variable quantum key distribution (CV-QKD) system, strong Einstein–Podolsky–Rosen entangled states can significantly boost the robustness and distance for secure communication. However, an inevitable bias of two entanglement quadratures may degrade the secret key rate and distance during random quadrature base switching. The bias originates from several interdependent factors in the generation, propagation, and detection of entangled states, which faces a challenge to be completely eliminated. Here, we analyze in detail the origin of the bias effect and report on a scheme of generating unbiased entangled states, whereby a − 10.7 ± 0.1 dB quadrature noise unbiased entanglement is first generated experimentally with two single-mode squeezed states. The unbiased quadrature correlations within the measurement bandwidth are expected to immensely enhance the key rate and secure distance for CV-QKD. [ABSTRACT FROM AUTHOR]