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Cax(Sr0.5Ba0.5)1-xNb2O6 [CSBN(x), x = 0.00, 0.10, 0.15, and 0.20] lead-Free ceramics were prepared by a traditional solid-state reaction technique. Dielectric, ferroelectric, and pyroelectric properties of CSBN(x) lead-Free ceramics were systematically investigated. The pyroelectric properties of CSBN(x) have been enhanced remarkably due to Ca addition and reached the maximum values at x = 0.15, with pyroelectric coefficient of 3.61 × 10-8 C/cm2 K and pyroelectric figure of merit of Fi = 172 pm/V, Fv = 0.021 m2/C, and Fd = 11.5 μPa-1/2, which are superior to other lead-free ferroelectric ceramics. These results indicate the potential of CSBN(x) ceramics for infrared detector applications. [ABSTRACT FROM AUTHOR]

Pyroelectric response mechanism of Ba0.70Sr0.30TiO3 ceramics under dielectric bolometer (DB) mode was investigated by dielectric and pyroelectric properties measurement. The variations of total, intrinsic, and induced pyroelectric coefficients (ptot, pint, pind) with temperatures and bias fields were analyzed. pint plays the dominant role to ptot through most of the temperature range and pind will be slightly higher than pint above T0. The essence of the enhancing effect of DC bias field on pyroelectric coefficient can be attributed to the high value of pint. This mechanism is useful for the pyroelectric materials (DB mode) applications. [ABSTRACT FROM AUTHOR]

The ferroelectric Ba0.6Sr0.4TiO3 (BST) and dielectric MgO composites with three different structures: columnar, layered, and spherical inclusion were prepared by spark plasma sintering (SPS). The microstructure and dielectric properties were investigated. Results show that the columnar composite exhibits an appreciable tunability (44.3%) as high as that of pure BST while the permittivity has been reduced from 5872 to 3998 at 10 kHz at room temperature, leading to a reduction of permittivity without deterioration of tunability in the bulk ceramics. This is a feasible way to balance the permittivity and the tunability, which is very promising for tunable devices application. [ABSTRACT FROM AUTHOR]

(Pb0.325Sr0.675)TiO3 (PST) ceramics were prepared by a traditional solid-state reaction technique. The dielectric and enhanced pyroelectric properties of PST ceramics were investigated under a DC bias field. The dielectric permittivity and dielectric loss of PST ceramics at Curie temperature were 2.97 × 10-4 and 0.006 without DC bias field, respectively. With a DC electric field of 0-500 V/mm, the maximum pyroelectric coefficient and the largest figure of merit (Fd) of PST ceramics were obtained, about 60 × 10-8 C cm-2 K-1 and 26 × 10-5 Pa-1/2, respectively. PST ceramics with such superior electric field enhanced pyroelectric properties have the potential for uncooled focal plane array detectors application. [ABSTRACT FROM AUTHOR]