1. Intriguing substitution of conducting layer triggered enhancement of thermoelectric performance in misfit-layered (SnS)1.2(TiS2)2
- Author
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Ning Liu, Xiong Zhang, Xiaoyuan Zhou, Ran Ang, Bin Kang, Cong Yin, Guoyu Wang, Qing Hu, Jun Tang, Yunwei Dou, and Tianyu Huang
- Subjects
010302 applied physics ,Materials science ,Physics and Astronomy (miscellaneous) ,Condensed matter physics ,Phonon scattering ,Chalcogenide ,Nanotechnology ,02 engineering and technology ,Power factor ,021001 nanoscience & nanotechnology ,Thermoelectric materials ,01 natural sciences ,chemistry.chemical_compound ,Effective mass (solid-state physics) ,Thermal conductivity ,chemistry ,Seebeck coefficient ,0103 physical sciences ,Thermoelectric effect ,0210 nano-technology - Abstract
We have systematically investigated the thermoelectric properties of misfit-layered chalcogenide (SnS)1.2(TiS2)2. Surprisingly, an unexpected Cu and Co substitution in the conducting TiS2 layer, acceptor dopant, can induce an exotic enhancement of thermoelectric performance. In particular, the value of dimensionless figure of merit ZT has increased by 33.3% and up to 0.42 at 720 K for Cu-substituted (SnS)1.2(Cu0.02Ti0.98S2)2. The present findings demonstrate that large effective mass and low carrier concentration are responsible for the emergence of large Seebeck coefficient and high power factor. Furthermore, the enhanced disorder effect due to the substitution accounts for the decrease of electronic thermal conductivity, while the increased phonon scattering of interlayer between SnS and TiS2 layers leads to the reduction of phononic thermal conductivity. Consequently, the Cu- and Co-substituted (SnS)1.2(TiS2)2 could be considered as a promising candidate of thermoelectric materials.
- Published
- 2017