1. Easy approach of highly electrochemical-active maricite NaFePO4 cathode for low cost and high rate sodium-ion batteries.
- Author
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Lu, Xinhao, Liu, Xiao, Li, Yuanhang, Wang, Congling, Zhang, Peng, Shi, Peng, Xu, Shuyin, Lyu, Yingchun, and Zhu, Chengjun
- Subjects
SODIUM ions ,CATHODES ,NEGATIVE electrode ,CARBON composites ,AMORPHOUS carbon ,ELECTROCHEMICAL electrodes - Abstract
Well-crystallized maricite NaFePO
4 is thermodynamically stable but electrochemically inactive toward sodium owing to the close packed framework. An efficient activation-approach is to construct amorphous composites with carbon by the complex and energy-intensive synthetic process. Here, a facile approach was proposed by the combination of low-temperature sintering and ball milling, which is environmentally friendly and suitable for scalable synthesis. Quasi-amorphous maricite NaFePO4 was first prepared via reducing the calcination temperature to 350 °C. Amorphous composite NaFePO4 /C was further obtained by ball milling of NaFePO4 -350 °C with super P, which delivers a reversible capacity of 134 mAh g−1 , closing to its theoretical capacity. More impressively, the NaFePO4 /C electrode still demonstrates decent capacity-retention of ∼75.4% over 1000 cycles, which is encouraging for future research. Pairing with hard carbon anode, the (+)NaFePO4 /C//HC(−) sodium-ion full cell delivers outstanding power density (169.9 Wh kg−1 calculated based on the total mass of positive and negative electrodes) and excellent cycling stability (84.5% capacity retention after 500 cycles at 5C), exhibiting powerful competitiveness compared with previously reported NaFePO4 based sodium-ion full cells. These results demonstrate the practical potential of maricite NaFePO4 cathode through low-temperature sintering. [ABSTRACT FROM AUTHOR]- Published
- 2023
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