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Over more than a century, several proposals have been made on the composition and technical features of the pictorial recipes used by Levantine prehistoric painters. In this paper all these proposals are surveyed and tested through systematic experiments to determine the technical affordance of pigments and binders in different pictorial recipes. Experimental results were then used as independent analytical parameters employed as diagnostic criteria to systematically study an archaeological sample of nine sites located in the Maestrazgo region (Spain) and their surroundings. Results reveal that out of 112 experimental recipes, only 16 afforded the production of paintings technically similar to Levantine rock art. [ABSTRACT FROM AUTHOR]

The Royal Artillery Factory of Seville in Spain originated from pre‐existing private bronze foundries dating from the 16th century. The paper analyses the stratigraphy of wall cladding in the areas traditionally known as the 'Old Foundry' and the 'New Foundry', through its characterization by optical microscopy, scanning electron microscopy with energy‐dispersive X‐ray spectrometry (SEM‐EDX), micro‐X‐ray fluorescence (μ‐XRF) and micro‐X‐ray diffraction (μ‐XRD), in order to analyse the metal deposits that have accumulated since the 17th century. The data obtained allowed the verification of the available historiographical information and the location of the original bronze smelting furnaces. The analysis of patinas deposited on the overlapping layers of lime also confirmed that neither the raw materials nor the composition of the alloys used presented any substantial changes. [ABSTRACT FROM AUTHOR]

Ancient quarries are intriguing archaeological sites, but their detailed recording is complex. This paper presents a cost-effective approach to mapping of the Roman quarry site of Pitaranha (Portugal-Spain). First, aerial photographs were acquired using a radio-controlled digital reflex camera attached to a Helikite, which allowed the acquisition of the necessary low-altitude aerial footage in the very unstable wind conditions above the quarry. Using computer vision algorithms, the resulting set of photographs was semi-automatically transformed into a Digital Surface Model (DSM) and a corresponding orthophotograph. Besides focusing on the acquisition and processing method, this paper evaluates the accuracy of the generated products. The orthophotograph proved to be satisfactorily accurate for 1:200 hard-copy mapping. [ABSTRACT FROM AUTHOR]

This paper studies the applicability of the Mean Shift algorithm as support in interpreting geophysical images produced, on this occasion, from magnetic prospection data. The data obtained from a magnetic survey carried out in Gilena (Seville province, Spain) by the La Rábida Archaeophysics Group will be used for the research. Its applicability is illustrated by comparing, on the one hand, some reduction-to-pole algorithms and on the other, the (well-known) k-means algorithm. Finally, the paper shows the results obtained by applying the Mean Shift algorithm as an alternative method to 'unsupervised clustering' of anomalies that appear in images obtained from geophysical data, in which the a priori knowledge of the number of classes is difficult or impossible. [ABSTRACT FROM AUTHOR]

This paper presents a quantification method for archaeological molluscs using fragmentation categories. By employing the data from nine prehistoric sites (13 000 to 5000 ; 15 700 to 5700 cal ) in Cantabrian Spain (northern Spain), it has been shown that traditional methods, based on one or two anatomical elements, systematically produce a loss in the minimum number of individuals (MNI) that is sometimes significant. This paper also proposes using fragmentation categories in the calculation of the fragmentation index. In addition, based on these indices, a reflection is made on the difficulty involved in associating the amount of fragmentation of the shells with the taphonomic processes that have occurred at the archaeological sites, especially in discerning which agents have caused the fragmentation. [ABSTRACT FROM AUTHOR]

This paper continues the characterization of the lead isotopic fingerprint of ancient copper mines in the north-west of Spain. In this work, the lead isotopic compositions found in copper ores from the La Profunda mine are presented. Azurites and malachites sampled from this deposit were subjected to lead isotope analysis by multicollector ICP- MS. The results showed a clear radiogenic lead signature compatible with the presence of uranium-rich minerals (such as zeunerite) in the same mining complex. Moreover, a rare copper artefact, found in the galleries of the mine during its modern exploitation, was also analysed and showed that local mineral was used for its manufacturing. [ABSTRACT FROM AUTHOR]

During the completion of the expansion works at the Museum of Pontevedra (Spain), a stretch of about 60 m of the medieval walled enclosure surrounding the historic city centre was discovered. Due to its value as a heritage element, the discovery of this archaeological structure required the implementation of preservation activities and exhaustive documentation so that future generations will be able to know and enjoy this piece of history. This paper presents digital models that reproduce the original structure of the wall using close-range digital photogrammetry, as well as orthophotos, which thoroughly document the dimensional and textural characteristics of the archaeological site. In addition to analysing the accuracy and validity of photogrammetry in the conservation of archaeological heritage, a methodology of data capture, processing and photogrammetry representation is evaluated. [ABSTRACT FROM AUTHOR]

This paper explores analytically the contemporary pottery-making community of Pereruela (north-west Spain) that produces cooking pots from a mixture of red clay and kaolin. Analyses by different techniques (XRF, NAA, XRD, SEM and petrography) showed an extremely high variability for cooking ware pottery produced in a single production centre, by the same technology and using local clays. The main source of chemical variation is related to the use of different red clays and the presence of non-normally distributed inclusions of monazite. These two factors induce a high chemical variability, not only in the output of a single production centre, but even in the paste of a single pot, to an extent to which chemical compositions from one ‘workshop’, or even one ‘pot’, could be classified as having different provenances. The implications for the chemical characterization and for provenance studies of archaeological ceramics are addressed. [ABSTRACT FROM AUTHOR]

Investigations of the siege of Islamic Alcalá la Vieja (Madrid, Spain) by Christian forces in the 12th century ce have depended on secondary sources proven to be unreliable and error‐laden. In a search for possible locations of trebuchets used by the Christian attackers, the option was for an interdisciplinary approach combining elements from archaeology, physics and spatial analysis. The discovery of stone projectiles near the Islamic fortress allowed for the application of projectile physics to the calculation of several effective firing ranges for each stone. Those outcomes, in combination with geographical information system (GIS) data, have revealed a possible location where Christian forces could have effectively deployed hybrid trebuchets as siege engines. [ABSTRACT FROM AUTHOR]

A rare open shallow crucible from the British Museum collection, excavated at the Bronze Age site of El Argar in south‐east Spain by Louis and Henri Siret, was studied using X‐radiography and scanning electron microscopy. The crucible has relatively thick walls, a spout and a non‐refractory fabric. It was used for melting copper alloys for various possible purposes, such as alloying, refining, recycling or before casting, at around 1100°C. Both arsenic and tin were detected in various places and concentrations in the analysed specimens. This crucible could have been used during the period of transition from arsenic‐rich copper to tin bronzes in the El Argar culture, or used for the recycling of arsenic‐rich copper artefacts being alloyed with tin to produce tin bronzes. This melting crucible is a rare example of its kind to have been investigated scientifically, as most crucibles from contemporary sites on the Iberian Peninsula are generally associated with smelting. This study has also crucially shed more light on the types of alloys and variety of activities undertaken during that transitional period between the use of arsenical copper and tin bronzes in this region. [ABSTRACT FROM AUTHOR]

We describe here the first combined isotopic and impurities study on 27 copper artefacts found in the north‐west of Spain. This study follows previous studies on the lead isotopic composition of copper ores in three local mines that were exploited during the Bronze Age. The levels of impurities found were clearly different from ingots and axes, with ingots having much higher levels of impurities. It was not possible to differentiate the origin of the artefacts only by the impurities present. On the other hand, the lead isotopic composition indicated that all artefacts were prepared from local ores, the 'La Profunda' mine being the most probable source for most artefacts that carried out a clear radiogenic lead signature. The copper isotopic composition seemed to be able to differentiate artefacts from the 'El Aramo' mine from those from the 'El Milagro' and 'La Profunda' mines. On the other hand, the antimony isotopic signature was not useful for source allocation. [ABSTRACT FROM AUTHOR]

Twenty-six samples from domestic assemblages of 9th-12th century Córdoba were subjected to electron microprobe analysis. The results reveal two main compositional types. The first, encountered in 13 of the samples, seems to result from the combination of plant ashes with high-impurity sand, and has some contemporary parallels from Syria and Egypt. The second type is a lead-soda-silica glass, encountered in a relatively high proportion of the glasses (11 of the 26 sampled), possibly formed by the addition of lead metal to existing glasses and with very few known parallels. These are among a very small number of results available to date on the chemical composition of glasses from medieval Spain, and the presence of a high proportion of lead-soda-silica glasses is particularly interesting, possibly indicating a technological practice unique to, or originating in, the western Muslim world. [ABSTRACT FROM AUTHOR]

The results of the first elemental and structural physicochemical analyses (SEM-EDX, TXRF, XRD, FTIR, GC and EDXRF) of Early Neolithic red pigment samples from the region of Valencia confirm one of the earliest uses of cinnabar (HgS) in Spain (5300 to 5000 cal bc). They also inform on the storage of massive quantities of hematite and the development of specific technologies of hematite-based paint production and use. The samples were recovered at the three most significant Early Neolithic sites of the Mediterranean coast of Spain: Cova de l'Or (Beniarrés, Alacant), Cova de la Sarsa (Bocairent, Valencia) and Cova Fosca (Vall d'Ebo, Valencia), which together have provided the most important European collection of Cardial ceramic ware (chronoculturally diagnostic of the Early Neolithic). [ABSTRACT FROM AUTHOR]

An essentially non-invasive electrochemical methodology addressed to the authentication of archaeological lead is described. The method is based on the record of the voltammetric response of nanosamples from the archaeological artefact mechanically transferred to a graphite 'pencil' electrode in contact with aqueous buffers. Three diagnostic criteria for authentication are described based on the appearance of: (i) oxidative dissolution signals for trace metals like copper, arsenic, antimony and, often, tin and silver accompanying stripping peaks for lead, (ii) peak potential shifts for reduction peaks for patination products, and (iii) the presence of reduction peaks for PbO2. The method is applied to the authentication of an Iberian lead plate from the Tossal de Sant Miquel (Llíria, Spain) site using a series of genuine and false pieces from different provenances in the Valencian region (Spain). [ABSTRACT FROM AUTHOR]

Ceramic fragments from the archaeological excavation of the Iberian-Roman city of Basti (Spain) were studied from a geochemical point of view and by applying a statistical tool to X-ray fluorescence data to discover similarities between ceramic materials. The analysis of these samples was completed by performing a mineralogical analysis, textural observation, and by characterizing the porous system and the colour of the pieces. Our results enabled us to identify the source area of the clayey raw material in the surroundings of Basti and to estimate the firing temperature of the ceramics. Differences in the chemistry were confirmed by characteristics of the pastes and the mineralogical composition of the pieces. Some samples show black cores, which would suggest the presence of organic matter in the raw material and fast firing of the ceramics. The main types of temper were quartz grains and gneiss fragments, although carbonate grains were also identified. Our evidence suggests that most of the samples were well fired. New silicate phases were found to be present in several samples. The mercury intrusion porosimetry verified and confirmed the firing temperature of non-carbonated samples. Colorimetry showed that the colour of the ceramics varied according to the amount of CaO that they contained. [ABSTRACT FROM AUTHOR]

The age of Neanderthal remains and associated sediments from El Sidrón cave has been obtained through different dating methods (14CAMS, U/TH, OSL, ESR and AAR) and samples (charcoal debris, bone, tooth dentine, stalagmitic flowstone, carbonate-rich sediments, sedimentary quartz grains, tooth enamel and land snail shells). Detrital Th contamination rendered Th/U dating analyses of flowstone unreliable. Recent 14C contamination produced spurious age-values from charcoal samples as well as from inadequately pretreated tooth samples. Most consistent 14C dates are grouped into two series: one between 35 and 40 ka and the other between 48 and 49 ka. Most ESR and AAR samples yielded concordant ages, ranging between 39 and 45 ka; OSL dating results permitted adequate bracketing of the sedimentary layer that contained the human remains. Our results emphasize the value of multi-dating approaches for the establishment of reliable chronologies of human remains. [ABSTRACT FROM AUTHOR]

The pigments, binders and execution techniques used by the Nasrids (1238–1492) to polychrome carpentry in the Hall of the Mexuar Palace at the Alhambra (Granada, Spain) were studied using optical microscopy, scanning electron microscopy with EDX analysis, selective staining techniques and gas chromatography – mass spectrometry. This pioneering investigation presents the first results of a research project devoted to filling gaps in the knowledge of Nasrid art, traditionally approached by stylistic studies. Moreover, it is essential for the polychromy conservation of the studied artworks, and will help to clarify historical and painting uncertainties in the Alhambra monument. The palette consists of a limited range of colours: white (lead-base pigment), red (cinnabar and red lead), blue (lapis lazuli), black (carbon-based) and false gold (golden tin). Tempera grassa was the painting technique identified. Two types of grounds were used: (i) gypsum in calligraphy decoration for the false gold technique, and (ii) synthetic minium in geometric drawings in carpentry. Organic insulating layers of linseed oil were used between paint strata. Artists applied synthetic minium to protect the wood (Juglans regia and conifer) against attack by xylophages. To lighten the surface darkened by this ground layer, powdered tin was added to achieve a metallic lustre. [ABSTRACT FROM AUTHOR]

Since little is known about the cuerda seca technique, our aim has been to complete an initial analysis of 11th-century cuerda seca by studying fragments from the 10th century (Pechina, Almería) and the 12th century (Mértola and Almería), so as to establish the diachronic evolution of this technique. Characteristics specific to cuerda seca ceramic glazes were investigated using scanning electron microscopy (SEM) and quantitative chemical analysis with energy-dispersive X-ray spectrometry (EDX). The chemical compositions of the different-coloured glazes (green, black, yellow and white) have given us valuable indications about the evolution of the technique. The opacification mode and the firing process were also investigated. With the help of cathodoluminescence (CL) and the study of modern ‘cuerda seca ’ glazed ceramics, new hypotheses regarding the number of firing stages, taking into account glaze and paste transformations and their interactions, are put forward. [ABSTRACT FROM AUTHOR]

Highlights the Fourth International Meeting on Bone Diagenesis which took place in Teruel, Spain in May 2000. Organizers of the meeting; Panel members.

The discovery of the workshop ‘Les Olleries Xiques’ in Paterna has provided a unique opportunity to analyse the raw materials, and in particular the recipes used in the production of the lustre decorations. Chemical and phase analyses of lustre raw materials and of lustre decorations belonging to the workshop pottery are shown. A comparison with existing ancient documentation on lustre recipes is also presented. [ABSTRACT FROM AUTHOR]

A solid-phase, non-chemical processing protocol was recently developed as a means of chemically characterizing archaeological ceramics by total reflection X-ray fluorescence (TXRF). Following this methodology, TXRF can provide semi-quantitative determinations for 18 elements with comparable levels of precision and accuracy for the majority of them in comparison with a clay reference material analysed by instrumental neutron activation (INAA). In order critically to assess the analytical capabilities of TXRF, a large sample set of Late Iron Age Spanish Celtiberian ceramics and modern clays was analysed both by TXRF and INAA. Semi-quantitative chemical data provided by TXRF and quantitative data provided by INAA were subjected to commonly used multivariate statistical methods as a way of evaluating the ability of the new technique to discriminate among different compositional groups. The comparison of the two data sets shows no significant discrepancies, thereby allowing support for the same archaeological interpretation. These results suggest that TXRF has potential applicability for compositional characterization of archaeological ceramics, providing data that are useful for provenance studies. [ABSTRACT FROM AUTHOR]