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1. Synthesis of newly enantiomerically pure 1,3-bis(2’-oxazolinyl)ferrocenes as potential pincer ligands

Author

Mauro Comes-Franchini, Bianca F. Bonini, Mariafrancesca Fochi, Elena Capito, and Alfredo Ricci

Subjects
chemistry.chemical_classification, Stereochemistry, Organic Chemistry, Regioselectivity, Ring (chemistry), Combinatorial chemistry, Pincer movement, lcsh:QD241-441, chemistry.chemical_compound, Dicarboxylic acid, Ferrocene, chemistry, Cyclopentadienyl complex, lcsh:Organic chemistry
Abstract

New enantiomerically pure 1,3-bis(2’-oxazolinyl)ferrocenes have been synthesized in good yields starting from 1,3-ferrocene dicarboxylic acid. Moreover, the possibility of performing a regioselective lithiation in position 2 of the disubstituted cyclopentadienyl ring of these compounds has been demonstrated.

Published
2006

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