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Aims. We aim to prove and diagnose the occurrence of nonthermal electron distributions in solar flare plasma using X-ray spectral observations. Methods. An M4.9 flare on 2003 January 7/8 was observed with the RESIK instrument in the 3−6 A wavelength range (2− 4k eV) and with RHESSI at energies above 6 keV. The temporal behavior of RESIK flare spectra has been analyzed for two different types of velocity distributions – a thermal (Maxwellian) distribution and a nonthermal plasma distribution of free electrons. The Si xiv, Si xiii ,a nd Sixiid satellite lines observed with RESIK in the 5−6 A range were used to determine the degree of deviation from Maxwellian, and the equivalent non-Maxwellian pseudo-temperature, τ. The diagnostics presented are sensitive to the shape of the distribution in the energy range where the maximum of the electron distribution occurs (where the bulk of electrons reside) and does not include the influence of the shape of the high-energy tail of the distribution. Under the assumption of a Maxwellian distribution of electron velocities, the plasma temperature was determined from an emission measure (EM) loci analysis and a differential emission measure (DEM) analysis of RESIK spectra. The high-energy end of the flare radiative emission was investigated through RHESSI spectral analysis. Results. The nonthermal analysis of RESIK spectra has shown that the largest deviations of the plasma electron distribution from Maxwellian appeared during the impulsive phase of the flare. The decay phase spectra had an almost isothermal character. The pseudotemperature, τ, reached its maximum around the peak time of the soft and hard X-ray fluxes. The temporal behavior of the temperatures derived from the thermal analysis was similar to the behavior of the nonthermal pseudo-temperature. The values of the pseudotemperature were consistent with the temperatures obtained in both thermal analyses, but lower than the temperatures derived from the slope of the RHESSI continua. In comparison with the synthetic isothermal or multithermal spectra, the nonthermal synthetic spectra fitted the observed Si xiid satellite lines much more closely (the error is less than 10%). The fluxes in the Si XIId satellite lines in isothermal or multithermal spectra have been underestimated by a factor of three or more in comparison to the observed fluxes. The value of this factor varies with time and it is different for the different satellite lines. Conclusions. Evidence was found for considerable deviations of the distribution of free electrons from Maxwellian in the plasma during a solar flare. These occurred mainly during the flare impulsive phase and can be diagnosed using existing X-ray spectral observations.

Aims. To perform a benchmark analysis for the recent version of the CHIANTI atomic database (v. 5.2) based on high-resolution solar flare X-ray spectra in the range 3.4-6.1 angstrom from the RESIK crystal spectrometer on the CORONAS-F spacecraft.Methods. A C5.8 flare occurring on 2003 February 22 was chosen for analysis. RESIK spectra of this flare include emission lines of He-like and H-like K, Ar, S, and Si, with some dielectronic lines. Initially, two independent plasma diagnostic techniques are employed: an emission measure (EM) loci analysis using the line flux and the line contribution function G(T-e, N-e), and a new method based on continuum fluxes and contribution functions. We further apply a differential emission measure (DEM) analysis, from which CHIANTI synthetic spectra are derived. The continuum from RESIK spectra is checked against simultaneous RHESSI and GOES observations. Comparisons of CHIANTI synthetic spectra with those from the MEKAL code in the 3.4-6.1 angstrom range are also presented.Results. The emitting plasma appears multi-thermal, having one dominant temperature component determined independently from the line and continuum EM loci and DEM analyses. Consistency between line and continuum emissions requires photospheric elemental abundances (Asplund et al. 2005), with a depleted sulphur abundance. With the exception of RESIK channel 4 (5.0-6.1 angstrom), we find overall very good agreement between the calculated and observed intensities. From comparisons with other instruments, RESIK's precision in the continuum level is confirmed to be within the estimated 20% uncertainties in the intensity calibration. We find general agreement between CHIANTI and MEKAL isothermal spectra, but we note that the atomic data for the Si XII and Si XIII ions contained in CHIANTI are more complete.Conclusions. RESIK observations of both lines and continua are suitable for characterising the properties of the flaring plasma such as temperature, emission measure and elemental abundance. These spectra can be used to evaluate any atomic database.

Aims. The detection of very hot plasma in the quiescent corona is important for diagnosing heating mechanisms. The presence and the amount of such hot plasma is currently debated. The SphinX instrument on-board the CORONAS-PHOTON mission is sensitive to X-ray emission of energies well above 1 keV and provides the opportunity to detect the hot plasma component. Methods. We analysed the X-ray spectra of the solar corona collected by the SphinX spectrometer in May 2009 (when two active regions were present). We modelled the spectrum extracted from the whole Sun over a time window of 17 days in the 1.34− 7k eV energy band by adopting the latest release of the APED database. Results. The SphinX broadband spectrum cannot be modelled by a single isothermal component of optically thin plasma and two components are necessary. In particular, the high statistical significance of the count rates and the accurate calibration of the spectrometer allowed us to detect a very hot component at ∼7 million K with an emission measure of ∼2.7 × 10 44 cm −3 . The X-ray emission from the hot plasma dominates the solar X-ray spectrum above 4 keV. We checked that this hot component is invariably present in both the high and low emission regimes, i.e. even excluding resolvable microflares. We also present and discuss the possibility of a non-thermal origin (which would be compatible with a weak contribution from thick-target bremsstrahlung) for this hard emission component. Conclusions. Our results support the nanoflare scenario and might confirm that a minor flaring activity is ever-present in the quiescent corona, as also inferred for the coronae of other stars.