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We study the recent outburst of the black hole candidate EXO 1846-031, which went into an outburst in 2019 after almost 34 yr in quiescence. We use archival data from the Swift/XRT, MAXI/GSC, NICER/XTI, and NuSTAR/FPM satellites/instruments to study the evolution of the spectral and temporal properties of the source during the outburst. The low-energy (2–10 keV) X-ray flux of the outburst shows multiple peaks, making it a multipeak outburst. Evolving type-C quasi-periodic oscillations are observed in the NICER data in the hard, hard-intermediate, and soft-intermediate states. We use the physical two-component advective flow (TCAF) model to analyze the combined spectra of multiple satellite instruments. According to the TCAF model, the accreting matter is divided into Keplerian and sub-Keplerian parts, and the variation in the observed spectra in different spectral states arises out of the variable contributions of these two types of accreting matter in the total accretion rate. Studying the evolution of the accretion rates and other properties of the accretion flow obtained from the spectral analysis, we show that the multiple peaks in the outburst flux arise out of the variable supply of accreting matter from the pile-up radius. We determine the probable mass of the black hole to be 10.4 − 0.2 + 0.1 M ⊙ from the spectral analysis with the TCAF model. We also estimate the viscous timescale of the source in this outburst to be ∼8 days from the peak difference of the Keplerian and sub-Keplerian mass-accretion rates. [ABSTRACT FROM AUTHOR]

G31.41+0.31 is a well known chemically rich hot molecular core (HMC). Using Band 3 observations from the Atacama Large Millimeter Array (ALMA), we have analyzed the chemical and physical properties of the source. We have identified methyl isocyanate (CH3NCO), a precursor of prebiotic molecules, toward the source. In addition to this, we have reported the presence of complex organic molecules (COMs) like methanol (CH3OH), methanethiol (CH3SH), and methyl formate (CH3OCHO). Additionally, we have used transitions from molecules like HCN, H13CO+, and SiO to trace the presence of infall and outflow signatures around the star-forming region. For the COMs, we have estimated the column densities and kinetic temperatures, assuming molecular excitation under local thermodynamic equilibrium (LTE) conditions. From the estimated kinetic temperatures of certain COMs, we found that multiple temperature components may be present in the HMC environment. Comparing the obtained molecular column densities between the existing observational results around other HMCs, it seems that the COMs are favorably produced in the hot core environment (∼100 K or higher). Though the spectral emissions toward G31.41+0.31 are not fully resolved, we find that CH3NCO and other COMs are possibly formed on grain/ice phase and populate the gas environment similar to other hot cores like Sgr B2, Orion KL, and G10.47+0.03. [ABSTRACT FROM AUTHOR]

The first identification of the argonium ion () toward the Crab Nebula supernova remnant was proclaimed by Herschel in the submillimeter and far-infrared domains. Very recently, the discovery of the hydro-helium cation () in the planetary nebula (NGC 7027) by SOFIA has been reported. The elemental abundance of neon is much higher than that of argon. However, the presence of neonium ions () is yet to be confirmed in space. Though the hydroxyl radicals (−OH) are very abundant in both neutral and cationic forms, hydroxyl cations of such noble gases (i.e., ArOH+, NeOH+, and HeOH+) are yet to be identified in space. Here, we employ a spectral synthesis code to examine the chemical evolution of the hydride and hydroxyl cations of the various isotopes of Ar, Ne, and He in the Crab Nebula filament and calculate their line emissivity and intrinsic line surface brightness. We successfully explain the observed surface brightness of two transitions of ArH+ (617 and 1234 GHz), one transition of OH+ (971 GHz), and one transition of H2 (2.12 μm). We also explain the observed surface brightness ratios between various molecular and atomic transitions. We find that our model reproduces the overall observed features when a hydrogen number density of ∼(104–106) cm−3 and a cosmic-ray ionization rate per H2 of ∼(10−11–10−10) s−1 are chosen. We discuss the possibility of detecting some hydride and hydroxyl cations in the Crab and diffuse cloud environment. Some transitions of these molecules are highlighted for future astronomical detection. [ABSTRACT FROM AUTHOR]

After hydrogen, oxygen, and carbon, nitrogen is one of the most chemically active species in the interstellar medium. Nitrogen-bearing molecules are very important as they are actively involved in the formation of biomolecules. Therefore, it is essential to look for nitrogen-bearing species in various astrophysical sources, specifically around high-mass star-forming regions where the evolutionary history is comparatively poorly understood. In this paper, we report on the observation of three potential prebiotic molecules, namely, isocyanic acid (HNCO), formamide (NH2CHO), and methyl isocyanate (CH3NCO), which contain peptide-like bonds (–NH–C(=O)–) in a hot molecular core, G10.47 + 0.03 (hereafter, G10). Along with the identification of these three complex nitrogen-bearing species, we speculate on their spatial distribution in the source and discuss their possible formation pathways under such conditions. A rotational diagram method under local thermodynamic equilibrium has been employed to estimate the excitation temperature and the column density of the observed species. The Markov Chain Monte Carlo method was used to obtain the best-suited physical parameters of G10 as well as line properties of some species. We also determined the hydrogen column density and the optical depth for a different continuum observed in various frequency ranges. Finally, based on these observational results, we have constructed a chemical model to explain the observational findings. We found that HNCO, NH2CHO, and CH3NCO are chemically linked with each other. [ABSTRACT FROM AUTHOR]

We study accretion flow dynamics of the Galactic transient black hole candidate (BHC) H 1743-322 during its 2010 outburst by analyzing spectral data using the two-component advective flow (TCAF; Keplerian and sub-Keplerian) solution after its inclusion in XSPEC as a local model. We compare our TCAF solution fitted results with combined disk blackbody (DBB) and power-law (PL) model fitted results and find a similar smooth variation of thermal (Keplerian or DBB) and non-thermal (PL or sub-Keplerian) fluxes/rates in two types of model fits. For a spectral analysis, 2.5-25 keV spectral data from the Rossi X-Ray Timing Explorer Proportional Counter Array instrument are used. From the TCAF solution fit, accretion flow parameters, such as Keplerian rate, sub-Keplerian rate, location of centrifugal pressure-supported shock, and strength of the shock, are extracted, providing a deeper understanding of the accretion process and properties of accretion disks around BHC H 1743-322 during its X-ray outburst. Based on the halo to disk accretion rate ratio, shock properties, accretion rates, and the nature of the quasi-periodic oscillations' (if observed) entire outburst is classified into four different spectral states: hard, hard-intermediate, soft-intermediate, and soft. From the time variation of intrinsic flow parameters, it appears that their evolutions in the declining phase do not retrace the path of the rising phase. Since our current model does not include magnetic fields, spectral turnover at energies beyond 500-600 keV cannot be explained. [ABSTRACT FROM AUTHOR]

The main focus of this paper is to explore the possibility of finding two deuterated isotopomers of H2Cl+ (chloronium) in and around the interstellar medium. The presence of a chloronium ion has recently been confirmed by the Herschel SpaceObservatory's Heterodyne Instrument for the far-infrared. It observed para-chloronium toward six sources in the Galaxy. To date the existence of its deuterated isotopomers (HDCl+ and D2Cl+) have not been discussed in the literature. We find that these deuterated gas phase ions could be destroyed by various ion-molecular reactions, dissociative recombination (DR), and cosmic rays (CRs). We compute all of the ion-molecular (polar) reaction rates by using the parameterized trajectory theory and the ion-molecular (non-polar) reaction rates by using the Langevin theory. For DR- and CR-induced reactions, we adopt two well-behaved rate formulas. We also include these rate coefficients in our large gas-grain chemical network to study the chemical evolution of these species around the outer edge of the cold, dense cloud. In order to study spectral properties of the chloronium ion and its two deuterated isotopomers, we have carried out quantum chemical simulations. We calculated ground-state properties of these species by employing second-order Moller-Plesset perturbation theory (MP2) along with quadruple-zeta correlation consistent (aug-cc-pVQZ) basis set. Infrared and electronic absorption spectra of these species are calculated by using the same level of theory. The MP2/aug-cc-pVQZ level of theory is used to report the different spectroscopic constants of these gas phase species. These spectroscopic constants are essential to predict the rotational transitions of these species. Our predicted column densities of D2Cl+, HDCl+, along with spectral information may enable their future identification around outer edges of cold, dark clouds. [ABSTRACT FROM AUTHOR]

In outburst sources, quasi-periodic oscillation (QPO) frequency is known to evolve in a certain way: in the rising phase, it monotonically goes up until a soft intermediate state is achieved. In the propagating oscillatory shock model, oscillation of the Compton cloud is thought to cause QPOs. Thus, in order to increase QPO frequency, the Compton cloud must collapse steadily in the rising phase. In decline phases, the exact opposite should be true. We investigate cause of this evolution of the Compton cloud. The same viscosity parameter that increases the Keplerian disk rate also moves the inner edge of the Keplerian component, thereby reducing the size of the Compton cloud and reducing the cooling timescale. We show that cooling of the Compton cloud by inverse Comptonization is enough for it to collapse sufficiently so as to explain the QPO evolution. In the two-component advective flow configuration of Chakrabarti-Titarchuk, centrifugal force-induced shock represents the boundary of the Compton cloud. We take the rising phase of 2010 outburst of Galactic black hole candidate H 1743-322 and find an estimation of variation of the α parameter of the sub-Keplerian flow to be monotonically rising from 0.0001 to 0.02, well within the range suggested by magnetorotational instability. We also estimate the inward velocity of the Compton cloud to be a few meters per second, which is comparable to what is found in several earlier studies of our group by empirically fitting the shock locations with the time of observations. [ABSTRACT FROM AUTHOR]

We investigate the effects of cooling of the Compton cloud on the outflow formation rate in an accretion disk around a black hole. We carry out a time-dependent numerical simulation where both the hydrodynamics and the radiative transfer processes are coupled together. We consider a two-component accretion flow in which the Keplerian disk is immersed into an accreting low-angular momentum flow (halo) around a black hole. The soft photons which originate from the Keplerian disk are inverse-Comptonized by the electrons in the halo and the region between the centrifugal pressure supported shocks and the horizon. We run several cases by changing the rate of the Keplerian disk and see the effects on the shock location and properties of the outflow and the spectrum. We show that as a result of Comptonization of the Compton cloud, the cloud becomes cooler with the increase in the Keplerian disk rate. As the resultant thermal pressure is reduced, the post-shock region collapses and the outflow rate is also reduced. Since the hard radiation is produced from the post-shock region, and the spectral slope increases with the reduction of the electron temperature, the cooling produces softer spectrum. We thus find a direct correlation between the spectral states and the outflow rates of an accreting black hole. [ABSTRACT FROM AUTHOR]