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A polarization beam splitter is an important component of modern optical system, especially a splitter that combines the structural flexibility of photonic crystal fiber and the optical modulation of functional material. Thus, this paper presents a compact dual-core photonic crystal fiber polarization beam splitter based on thin layer As2S3. The mature finite element method was utilized to simulate the performance of the proposed splitter. Numerical simulation results indicated that at 1.55 μm, when the fiber device length was 1.0 mm, the x- and y-polarized lights could be split out, the extinction ratio could reach −83.6 dB, of which the bandwidth for extinction ratio better than −20 dB was 280 nm. It also had a low insertion loss of 0.18 dB for the x-polarized light. In addition, it can be completely fabricated using existing processes. The proposed compact polarization beam splitter is a promising candidate that can be used in various optical fields. [ABSTRACT FROM AUTHOR]