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We retrieved lower stratospheric vertical profiles of O3, HNO3, and HCl from solar spectra taken with a ground-based Fourier-Transform infrared spectrometer (FTIR) installed at Syowa Station, Antarctica (69.0° S, 39.6° E) from March to December 2007 and September to November 2011. This was the first continuous measurements of chlorine species throughout the ozone hole period from the ground in Antarctica. We analyzed temporal variation of these species combined with ClO, HCl, and HNO3 data taken with the Aura/MLS (Microwave Limb Sounder) satellite sensor, and ClONO2 data taken with the Envisat/MIPAS (The Michelson Interferometer for Passive Atmospheric Sounding) satellite sensor at 18 and 22 km over Syowa Station. HCl and ClONO2 decrease occurred at both 18 and 22 km, and soon ClONO2 was almost depleted in early winter. When the sun returned to Antarctica in spring, enhancement of ClO and gradual O3 destruction were observed. During the ClO enhanced period, negative correlation between ClO and ClONO2 was observed in the time-series of the data at Syowa Station. This negative correlation was associated with the distance between Syowa Station and the inner edge of the polar vortex. We used MIROC3.2 Chemistry-Climate Model (CCM) results to see the comprehensive behavior of chlorine and related species inside the polar vortex and the edge region in more detail. From CCM model results, rapid conversion of chlorine reservoir species (HCl and ClONO2) into Cl2, gradual conversion of Cl2 into Cl2O2, increase of ClO when sunlight became available, and conversion of ClO into HCl, was successfully reproduced. HCl decrease in the winter polar vortex core continued to occur due to the transport of ClONO2 from the subpolar region to higher latitudes, providing a flux of ClONO2 from more sunlit latitudes into the polar vortex. Temporal variation of chlorine species over Syowa Station was affected by both heterogeneous chemistry related to Polar Stratospheric Cloud (PSC) occurrence deep inside the polar vortex, and transport of an NOx-rich airmass from lower latitudinal polar vortex boundary region which can produce additional ClONO2 by reaction of ClO with NO2. The deactivation pathways from active chlorine into reservoir species (HCl and/or ClONO2) were found to be highly dependent on the availability of ambient O3. At an altitude where most ozone was depleted in Antarctica (18 km), most ClO was converted to HCl. However, at an altitude where there were some O3 available (22 km), additional increase of ClONO2 from initial value can occur, similar to the case in the Arctic. [ABSTRACT FROM AUTHOR]

To understand and project future ozone recovery, understanding of mechanisms related to polar ozone destruction is crucial. For polar stratospheric ozone destruction, chlorine species play an important role, but detailed temporal evolution of chlorine species in the Antarctic winter is not well understood. We retrieved lower stratospheric vertical profiles of O3, HNO3, and HCl from solar spectra taken with a ground-based Fourier-Transform infrared spectrometer (FTIR) installed at Syowa Station, Antarctica (69.0° S, 39.6° E) from March to December 2007 and September to November 2011. We analyzed temporal variation of these species combined with ClO, HCl, and HNO3 data taken with the Aura/MLS (Microwave Limb Sounder) satellite sensor, and ClONO2 data taken with the Envisat/MIPAS (The Michelson Interferometer for Passive Atmospheric Sounding) satellite sensor at 18 and 22 km over Syowa Station. When the stratospheric temperature over Syowa Station fell below polar stratospheric cloud (PSC) saturation temperature in early winter, PSCs started to form and heterogeneous reaction on PSCs convert chlorine reservoirs into reactive chemical species. HCl and ClONO2 decrease occurred at both 18 and 22 km, and soon ClONO2 was almost depleted in early winter. When the sun returned to Antarctica in spring, enhancement of ClO and gradual O3 destruction were observed. During the ClO enhanced period, negative correlation between ClO and ClONO2 was observed in the time-series of the data at Syowa Station. This negative correlation was associated with the distance between Syowa Station and the inner edge of the polar vortex. Temporal variation of chlorine species over Syowa Station was affected by both heterogeneous chemistry related to PSC occurrence deep inside the polar vortex, and transport of an NONOx"-rich airmass from lower latitudinal polar vortex boundary region which can produce additional ClONO2 by reaction between ClO and NO2. We used MIROC3.2 Chemistry-Climate Model (CCM) results to see the comprehensive behavior of chlorine and related species inside the polar vortex and the edge region in more detail. Rapid conversion of chlorine reservoir species (HCl and ClONO2) into Cl2, gradual conversion of Cl2 into Cl2O2, increase of ClO when sunlight became available, and conversion of ClO into HCl, was successfully reproduced by the CCM. HCl decrease in the winter polar vortex core continued to occur due to the transport of ClONO2 from the subpolar region (55-65º S) to higher latitudes (65-75º S), providing a flux of ClONO2 from more sunlit latitudes into the polar vortex. The deactivation pathways from active ClO into reservoir species (HCl and/or ClONO2) were found to be highly dependent on the availability of ambient O3 and NOx". At an altitude where most ozone was depleted in Antarctica, most ClO was converted to HCl. However, when there were some O3 and NOx" available, super-recovery of ClONO2 can occur, similar to the case in the Arctic. [ABSTRACT FROM AUTHOR]

The first observations made by a complete PANSY radar system (Program of the Antarctic Syowa MST/IS Radar) installed at Syowa Station (39.6 °E, 69.0 °S) were successfully performed from March 16-24, 2015. Over this period, quasi-half-day period (12 h) disturbances in the lower mesosphere at heights of 70 km to 80 km were observed. Estimated vertical wavelengths, wave periods and vertical phase velocities of the disturbances were approximately 13.7 km, 12.3 h and -0.3 m s-1, respectively. Under the working hypothesis that such disturbances are attributable to inertia-gravity waves, wave parameters are estimated using a hodograph analysis. The estimated horizontal wavelengths are longer than 1100 km, and the wavenumber vectors tend to point northeastward or southwestward. Using the non-hydrostatic numerical model with a model top of 87 km, quasi 12 h disturbances in the mesosphere were successfully simulated. We show that quasi 12 h disturbances are due to wave-like disturbances with horizontal wavelengths longer than 1400 km and are not due to semi-diurnal migrating tides. Wave parameters, such as horizontal wavelengths, vertical wavelengths and wave periods, simulated by the model agree well with those estimated by the PANSY radar observations under the above-mentioned assumption. The parameters of the simulated waves are consistent with the dispersion relationship of the inertia-gravity wave. These results indicate that the quasi 12 h disturbances observed by the PANSY radar are attributable to large-scale inertia-gravity waves. By examining a residual of the nonlinear balance equation, it is inferred that the inertia-gravity waves are likely generated by the spontaneous radiation mechanism of two different jet streams. One is the mid-latitude tropospheric jet around the tropopause while the other is the polar night jet. Large vertical fluxes of zonal and meridional momentum associated with large-scale inertia-gravity waves are distributed across a slanted region from the mid-latitude lower stratosphere to the polar mesosphere in the meridional cross-section. Moreover, the vertical flux of the zonal momentum has a strong negative peak in the mesosphere, suggesting that some large-scale inertia-gravity waves originate in the upper stratosphere. [ABSTRACT FROM AUTHOR]