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Start Over Author "Boyd, Jeffery M." Journal biochemistry
1 results on '"Boyd, Jeffery M."'

1. The stereoselectivity and catalytic properties of Xanthobacter autotrophicus 2-[(R)-2-hydrooxypropylthio]ethanesulfonate dehydrogenase are controlled by interactions between C-terminal arginine residues and the sulfonate of coenzyme M

Author

Clark, Daniel D., Boyd, Jeffery M., Ensign, Scott A., Goodman, Myron F., and Greenberg, Marc M.

Subjects
Enzymes -- Research, Biological sciences, Chemistry
Abstract

In the study the features of substrate and enzyme imparting sterospecificity are investigated for R-HPCDH. The effects of linear alkylsulfonates on the kinetics and stereoselectivity of aliphatic ketone reduction were investigated. The results support a model where specific sulfonate-arginine interactions dictate the catalytic properties and stereospecificity of R-HPCDH.

Published
2004

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