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Hydrothermal carbonization (HTC) is a promising process for the upgrading of wet biomass residues. Models of HTC processes, in particular at continuous pilot-scale, are needed to move HTC from lab-scale to industrial scale. This study presents a process model for mild HTC, dewatering and conversion to intermediate energy carriers (bio-pellets and biogas for power and/or heat production) of three wet biomass residue streams: paper sludge, olive pomace and orange peels, based on lab- and pilot-scale experiments. In addition, the process energy efficiency and feedstock utilization of the HTC process is calculated and compared with conventional treatment options for the chosen residues, i.e., direct anaerobic digestion (olive pomace, orange peels) or combustion after conventional dewatering (paper sludge). The process model indicates that the HTC pilot-scale process is much more efficient in terms of feedstock utilization to produce heat and/or power than the reference scenarios. The process energy efficiency of the HTC process (pilot-scale) was calculated to be 26 %, 63 % and 40 % for paper sludge, olive pomace and orange peel feedstocks, respectively. For all feedstocks, both the solid and liquid-generated products are equally important for improving the overall process energy efficiency. This study demonstrates the potential benefits of HTC processes for upgrading wet biomass waste streams based on continuous pilot-scale data. • Hydrothermal carbonization successfully upgraded wet biomass residues for energy. • Hydrothermal carbonization was more efficient for heat/power than reference cases. • Solid and liquid products are both important to improve process energy efficiency. [ABSTRACT FROM AUTHOR]

Densification is the most effective forming technology, the production of which, pellets are the most intensive energy content of biomass solid fuels. Increasing the overall utilization efficiency of bioenergy, extending available types of wastes and residues for pelleting, and improving the pellet quality comprehensively are necessary. This paper reviewed feedstocks used for pelleting, binding mechanism of biomass pellets, and evaluation systems of pellet qualities. To extend the supply amounts and improve the qualities of raw biomass, various feedstocks and formulation recipes were classified based on their regions, sources, and species. And applicable objects and conditions of several different pretreatment technologies for feedstocks were compared. Physical properties and biochemical analyses are also concluded to evaluate the flowability, compactibility, and potential characteristics as solid fuel. For a better understanding of energy consumption and conversion during the densification process, pelleting devices and binding mechanism are elaborated. Associations and differences between single pelleting press in lab-scale and industrial pelleting in pilot-scale are also discussed. Suggestions are proposed for the optimization design of pelleting devices and processes for different feedstock densification. Lastly, relationships between operating parameter factors of pelleting process and pellet quality are presented. This review could provide theoretical analyses for powder compression, new insights for waste to energy, and guidance for achieving global peak carbon and environmental strategic objectives. [Display omitted] • Biomass feedstocks and recipes used for pelleting are reviewed. • Pelleting process is explained from theoretical and experimental aspects. • Durability and water sorption of biomass pellets are discussed. • Suggestions are given for optimizing pelleting process and mechanical device design. • New methods and concepts in industrial pelleting are presented. [ABSTRACT FROM AUTHOR]

The interactions among chlorine (Cl), sulfur (S), and alkaline and alkaline-earth metals (AAEMs) are the critical factors that affect the formation, transformation, and deposition of ash during biomass and coal gasification and combustion. These issues cause slagging, agglomeration, corrosion, and other problems related to the safety performance of gasifiers and boilers. A better understanding of the determination methods, modes of occurrence, migration routes, and control technologies of Cl and S is the basis for clean and efficient utilization of biomass and coal. The paper summarizes the research work in this field, namely: (1) The modes of Cl and S occurrence in biomass and coal are introduced, mainly in different forms of inorganic and organic Cl/S compounds; (2) The principles, merits and demerits of quantitative determination methods for Cl and S are sorted out and compared; (3) The migration routes of Cl and S, mainly related to their modes of occurrence, reaction evolution, temperature, and atmosphere; and (4) The interactions among Cl, S, and AAEMs and its induced issues, especially the challenging problems related to ash, including alkali-induced slagging, silicate melt-induced slagging (ash fusion), agglomeration, and corrosion. Finally, ecological and technological significance of the Cl and S release is discussed. This knowledge is of great significance to effectively control the emission of Cl and S pollutants, stable operation of gasifiers and boilers, cleaner and more efficient utilization of coal, as well as to diminish the consumption of fossil energy and heighten the availability of renewable energy in such thermochemical conversion processes. • Migration routes of chlorine and sulfur are elucidated. • Interactions among chlorine, sulfur, and AAEMs are summarized. • Ecological and technical significance of chlorine and sulfur release is discussed. [ABSTRACT FROM AUTHOR]

Recirculation of hydrothermal carbonization (HTC) process water (PW) has been revealed as an effective strategy to promote the recovery of lost dissolved organics in the spent solvent. However, the role of operating parameters such as temperature, time and solid load during recirculation needs to be clarified and better investigated in order to achieve a successful PW valorization. In this paper, the effects of different reaction conditions during HTC with PW recirculation were studied by using orange peel waste as feedstock. The results showed that strong synergistic interactions occurred between the biomass and the recycled solvent, leading to a hydrochar mass yield increase between 0.5 and 11 wt% on a dry basis (d.b.), according to the reaction conditions. PW recirculation, especially at low conversion severity and solid load, increased hydrochar carbon content while drastically reduced the oxygen fraction. The reason was probably related to promoted dehydration and decarboxylation. As result, carbon and energy yields were respectively increased by 26.1 % and 27.0 %, on average. The energy balance outcomes showed that the energy recovery rose up to 8 times by recycling PW compared to phases with deionized water as HTC solvent. [Display omitted] • Hydrochar recovery enhancement is obtained by solvent recirculation. • Intense synergistic effects in hydrochar formation occur at low temperatures. • Dehydration and decarboxylation are promoted by solvent recycling. • Hydrochar carbon retention is increased by 6.2 % after recirculation at 180 °C. • Process water recirculation improves the conversion energy efficiency. [ABSTRACT FROM AUTHOR]

Chemi-mechanical pulping (CMP) is a typical high-yield pulping technology to produce various papers and paperboards due to its high yield and high fiber properties. However, it is challenging to further improve its energy efficiency without the scarification of fiber quality. To attack this challenge, herein we study the effects of different hemicellulose pre-extraction on the viscoelasticity of wood cell wall, the energy efficiency, and product properties in chemi-mechanical pulping (CMP) process. Hardwood was first pretreated by NaOH to hydrolyze the benzyl ester bonds that link lignin with hemicellulose, aiming to partially remove hemicellulose and weaken the inter-fiber connections. Then, the hemicellulose-extracted wood underwent refining. The chemical distributions of wood, fiber morphologies, fiber surface fibrillation, energy consumption, and paper properties were extensively studied. The results showed that a 40.8% removal of hemicellulose corresponded to a 90.3% reduction in wood storage modulus (E') and a 68.3% decrease in specific refining energy consumption. Moreover, the weaker connections between microfibrils in the secondary layer, caused by hemicellulose extraction, promoted fiber surface fibrillation during pulp refining. The study elucidates the nonnegligible role of hemicellulose as the linking "bridge" between lignin and cellulose. It also provides a new mechanism in addition to the current classic pulping mechanism including lignin chemical/thermal softening and cellulose swelling in both CMP and chemi-thermomechanical pulp (CTMP). This study offers a feasible and efficient approach to extract hemicellulose from hardwood to reduce the refining energy without scarification of fiber quality, therefore, it holds promise for advanced and greener biorefineries. [Display omitted] • The mechanism of chemical-mechanical pulping about hemicellulose was supplemented. • Removal 40.8% of hemicellulose reduced wet woods' storage modulus by 90.3%. • LC ester bonds hydrolysis weakens connection inter-fibers and inter-microfibrils. • Wood de-hemicellulose optimized fiber separation and fibrillation in refining. [ABSTRACT FROM AUTHOR]

The application of compressed biogas (CBG) in day-to-day livelihood has garnered significant attention in modern day era. It is considered as a potential solution to curb the increasing energy demand and other environmental concerns. The process involves anaerobic digestion (AD) (hydrolysis, acidogenesis, acetogenesis and methanogenesis) of organic substrate under an optimum operating condition (pH, temperature, etc.) via anaerobic microorganisms. This paper aims to describe some major facts about different technological options related to pre-treatment, AD, cleaning and up-gradation system. It also highlights the practical challenges related to high investment cost, inadequate infrastructure, clearance and approval issues, poor feedstock supply chain management etc. in adaption of CBG plants in India. The review examines the significance of both dry and wet continuous digester systems, which includes its advantages and challenges, considering factors, such as feedstock characteristics, process stability, and operational efficiency. It was also found that the type of feedstock and its availability in existing market plays a vital role in smooth functioning of CBG plants. Therefore, the study presents a comprehensive review discussing potential feedstock readily available for CBG plants in Indian market. It was concluded that the usage of agricultural waste (such as Napier grass) has higher CBG potential compared to other feedstock. At the same time, the study presents a broader aspect to policy makers and governing authorities to reframe the existing structure for financial assistantship, regulatory laws, subsidiary schemes etc. for CBG plant owners. It also gives an opportunity to technocrats, industrialist and investors to come-up with an indigenous technology with in-house manufacturing units to promote CBG production in India. [Display omitted] • India has 46 compressed biogas plants with an overall capacity of 272 tonnes/day. • Elaborated the significance of both dry and wet continuous digester systems. • Setting-up a compressed biogas plants requires high investment and operational cost. • Potential market for bio-fuels and bio-fertilizer needs to be explored in India. • Existing financial assistantship and subsidiary schemes need transformation. [ABSTRACT FROM AUTHOR]

The paper presents a novel thermodynamic modeling approach of a pilot solar biomass system for bio-methane energy production and wastewater treatment by creation of two packages (STSB and MHPB) modeling platform under TRNsys studio software. Indeed, several newly developed mathematical schemes using the communicating elements: a new Multi-stage air to water Heat Pump, a new Vacuum Tube solar Collector (VTC), thermodynamic storage, and a biogas reactor) have been validated by experiment. The work presents and discusses two scenarios (packages), the first one –STSB- concerns the pilot solar-biomass system, and uses only renewable energy for the bio-methane production by anaerobic digestion mechanism under the mesophilic conditions (±35 °C to ±42 °C), The second scenario consists of a modeling Multi-stage Heat Pump Biomass reactor (MHPB). The packages developed have been tested for industrial case study. A validation process of two scenarios with experimental tests of a 500 L reactor -for the biomass of the cardboard paper-proves a good agreement, where the errors band is about 1% for STSB and 1.5% for the MHPB package. The biogas reactor treats about 900 (m3/year) liquid biomass (3 m3/day). The prediction results indicate that the biogas production attaint 51 (m3) per year. According to the biogas composition analysis, the bio-methane represents 74%, leading to prediction results of 38 (m3) per year of bio-methane for the case study.. Further, the extended results from the modeling packages platform indicate that for this installation type of 700 m3, the bio-methane (CH4) production is estimated of 52 836 (m3) per year, representing 64% of the total fuel consumption for the current case of cardboard recycling and packaging company. • Two free packages (STSB and MHPB) was developed for simulation the solar biogas process. • An experimental validation process of the two packages proves a good agreement of less than 1% for STSB and 1.5% for MHPB. • The reliability of the two packages was demonstrated under the climatic conditions input of 1 min as a time step over a complete one year. • The solar bio-methane reactor unit achieved a satisfactory annual thermal efficiency of 58% for all considering cases and 42% as an efficiency conversion of biogas production. [ABSTRACT FROM AUTHOR]

This paper makes projections of the theoretical and technical potentials of bioenergy supply for 2050. The projections consider changes in available land for bioenergy and food for the global demand and advancements in yield, productivity, expansion of bio-waste recovery, and energy conversion. We present a literature review on projections. We introduced a novel logical and transparent forecasting model. Three future scenarios were established: business as usual (BUS), optimistic trends (OPT), and full adaptation response (FAR). The projection is carried out based on four adjusting factors. An uncertainty analysis was carry-out based on a Monte-Carlo method. Projections of bioenergy production in 2050 were compared with other projections in the literature. The FAR scenario showed that it would be possible to produce twenty-one times the current primary bioenergy supply and to even supply all global primary energy demand in 2050, mostly by energy crops. The assumptions adopted for the BUS and OPT scenarios make their projections more likely. Therefore, the contribution of bioenergy in the global energy matrix is expected to be between 64 and 313 EJ (7.5%–37%) in 2050. There would be a significant change in the composition of the bioenergy supply from today's mostly firewood to energy crops and biowastes. The technical potential for fuel and electric power mostly follow the supply trends for primary bioenergy (theoretical). The potential avoided greenhouse emissions are estimated. The heuristics and the level of transparency of the novel model will allow adjustments and exploration of other scenarios as time passes. • Novel model for projections of the potential of global primary bioenergy supply. • Bioenergy supply potential is shown for 11 different groups of biomass. • Global primary bioenergy supply could increase up to 6 times by 2050 (37% of demand). • Full adaptation response scenario could meet 100% of the global energy demand. • Bioenergy can play a major role in the global energy supply. [Display omitted] [ABSTRACT FROM AUTHOR]

Supercritical water oxidation (SCWO) is an effective, promising technology for destroying almost all kinds of organic waste with the advantage of high removal efficiency and low residence time, and without producing pollutant byproduct. The chemical energy of organic pollutants can be considered as an emerging renewable energy source. As a high-temperature and pressure process, an immense energy demand is required in the pressurization and preheating sections. On the other side, the reactor effluent has a great potential for energy recovery because of the great amount of heat released during the SCWO reaction combined with the previous energy input. Thus, SCWO is not only an organic waste treatment process but also an energy conversion and utilization system. The application of SCWO has been extended to the clean, efficient utilization of low-quality fuels such as high-sulfur coal, heavy oils, and biomass instead of conventional combustion, hydrothermal spallation drilling in geothermal energy production, and heavy oil recovery. However, energy consumption cost is still rather high in the actual process due to insufficient equipment performance, unreasonable energy system integration, and selection of an anti-corrosion and salt plugging reactor. Thus, a systematic, in-depth analysis on energy conversion and utilization in SCWO is conducted for the first time in the paper. The mechanism of exergy destruction analyses indicates that reducing enthalpy change and energy level difference are critical to reducing energy consumption. Suggestions on improving energy efficiency are proposed in the preheating stage, chemical exergy release, and reactor design. [Display omitted] • Energy conversion and utilization in each stage of an SCWO system are analyzed. • Research methods and evaluation parameters for energy utilization are summarized. • Main factors affecting energy efficiency are summarized and analyzed. • The mechanism of exergy destruction is analyzed to reduce energy consumption. • Suggestions on improving energy efficiency are proposed. [ABSTRACT FROM AUTHOR]

The link between energy and climate change is fundamental - energy accounting for two-thirds of global greenhouse gas emissions. Of all countries, those of the Arabian Peninsula are synonymous with energy and the supply and use of fossil fuels. However driven by commitments to international climate change agreements the Gulf Cooperation Council (GCC) countries have been developing alternative energy strategies with targets for renewables. This paper presents the outputs of biomass resource modelling analyses that identify bioenergy opportunities across the region. Municipal wastes are found to represent a leading opportunity for bioenergy with a combined 19.35 Mtpa of resource across the GCC currently being sent to landfill that could otherwise be used for energy. The research finds that up to 22.5% of GCC country electricity could be generated from bioenergy technologies fuelled by indigenous biomass resources. Interviews were undertaken with Director-level GCC individuals from industry and government and a survey was facilitated to gain an understanding of perceptions of bioenergy and the potential barriers to its greater deployment. There was majority support for renewable technologies and for bioenergy, however a majority of respondents were found to be 'not willing' or 'unsure' when asked if they would be willing to take any individual actions such as recycling to support bioenergy schemes. High availability of cheap fossil fuels, stimulated by fossil fuel subsidies is identified as the greatest barrier to renewables. The GCC's commitment to international climate and sustainability targets represents an opportunity to develop a strategy to phase out fossil fuels. • Focus GCC Countries: Bahrain, Kuwait, Oman, Qatar, Saudi Arabia & the UAE • 19.35 Mtpa of MSW resource currently sent to landfill, could be used for bioenergy • 1.68 Mtpa of crops residues & 25.52 Mtpa of animal wastes could be used for bioenergy • Bioenergy from indigenous resources could balance up to 22.5% of power. • Expert stakeholder & GCC public supportive of greater deployment of bioenergy [ABSTRACT FROM AUTHOR]