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Microwave pyrolysis of moso bamboo over bamboo-based biochar catalyst was conducted to achieve the bio-oil upgrading and high quality syngas production. The influence of the biochar on bamboo pyrolysis involving the temperature rise, product yield, and bio-oil and gas compositions was studied. The gas production was facilitated by the biochar mainly at the cost of the bio-oil, indicating the biochar had an excellent activity for the bio-oil cracking. The main compositions in bio-oil were acetic acid and phenol with the total contents ranging from 73.145% to 82.84% over the biochar catalysts, suggesting the upgrading of the bio-oil were achieved. The biochar exerted a positive effect on the syngas (CO + H 2 ) production with the maximum content reaching up to 65.13 vol% at the 20 wt% addition amount of biochar under microwave condition. The biochar became more effective on the bio-oil upgrading and syngas production under microwave heating than conventional heating. [ABSTRACT FROM AUTHOR]

The effect of iron(III) ion on microwave pyrolysis of moso bamboo was investigated. Hydrofluoric acid washing was used as a pilot process to demineralize moso bamboo in order to eliminate the influences of the other inorganics contained in moso bamboo itself. The results indicated that the addition of iron(III) ion increased the maximal reaction temperatures under microwave condition dependent on the amount of the added iron(III) ion. The production of the non-condensable gases was promoted by the addition of iron(III) ion mainly at the expense of liquid products. Iron(III) ion exhibited the positive effect for syngas production and inhibited the formation of CO 2 and CH 4 . The formation of Fe 2 O 3 and Fe 3 O 4 was found during microwave pyrolysis and the mechanism of the two metallic oxides formation was described in this work. [ABSTRACT FROM AUTHOR]