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Your search keyword '"Gennadii V. Dolgushin"' showing total 2 results
Start Over Author "Gennadii V. Dolgushin" Journal bulletin of the academy of sciences of the ussr division of chemical science
2 results on '"Gennadii V. Dolgushin"'

1. 31Cl NQR spectra of compounds in Cl3CCH2CXRR' series

Author

Valentin P. Feshin, M. Gaek, Z. Yanoushek, Gennadii V. Dolgushin, and M. G. Voronkov

Subjects
Crystallography, Series (mathematics), Group (periodic table), Computational chemistry, Chemistry, Telomerization, Chlorine atom, Chlorine, Molecule, chemistry.chemical_element, General Chemistry, Spectral line, Mutual influence
Abstract

In molecules in the series Cl3CCH2CClRR', the substituents R and R' virtually do not affect the chlorine atoms of the Cl3C group, while the NQR frequency of the chlorine atom of the CClRR' group correlates satisfactorily with the σ* constants of these substituents. The regularities observed in the mutual influence of the atoms in the molecules of the studied series indicate that the previously assumed structure of some products of radical telomerization of Cl3CH with H2C=CHCl is erroneous.

Published
1990

2. Question of the complexation of tetrachlorostannane with benzyl chloride

Author

M. G. Voronkov, I. M. Lazarev, Gennadii V. Dolgushin, and Valentin P. Feshin

Subjects
chemistry.chemical_compound, Benzyl chloride, Chemistry, Condensation, Liberation, Organic chemistry, General Chemistry, Catalysis
Abstract

The condensation of PhCH2Cl with the liberation of HCl catalyzed by SnCl4, occurs in the PhCH2Cl-SnCl4. system. The proposal of the existence of a cis-octahedral complex, 2PhCH2Cl· SnCl4, was proved erroneous.

Published
1987

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