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Your search keyword '"L. Korshunov"' showing total 2 results
Start Over Author "L. Korshunov" Journal bulletin of the academy of sciences of the ussr division of chemical science
2 results on '"L. Korshunov"'

1. Methanolysis of stereoisomeric 4?-chloro-3,10-epoxycaranes

Author

Z. G. Isaeva, R. L. Korshunov, Yu. Ya. Efremov, G. I. Kovylyaeva, and G. A. Bakaleinik

Subjects
chemistry.chemical_compound, Stereospecificity, Chemistry, Oxide, Organic chemistry, General Chemistry, Ring (chemistry), Cleavage (embryo), Catalysis
Abstract

Under conditions of acid methanolysis, the stereoisomeric 4β-chloro-3α,10- and 3β,10-epoxycaranes form addition products with predominant cleavage of the oxide ring at the C10-0 bond, while on alkaline catalysis they form products with cleavage of the C3-0 bond.

Published
1987
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2. Reaction of dimethyl sulfite with dimethylaminomethyl derivatives

Author

S. V. Baires, R. L. Korshunov, B. E. Ivanov, S. S. Krokhina, Yu. Ya. Efremov, and V. B. Ivanov

Subjects
chemistry.chemical_compound, Chemistry, Yield (chemistry), Product (mathematics), Organic chemistry, Dimethyl sulfite, General Chemistry
Abstract

The reaction of dimethylaminomethyl derivatives Me2NCH2X with dimethyl sulfite proceeds by analogy with the Arbuzov rearrangement under mild conditions. The yield of the rearrangement product increases with increasing nueleophilicity of (X).

Published
1986
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