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Start Over Author "Hijji, Yousef" Journal canadian journal of chemistry
1 results on '"Hijji, Yousef"'

1. Alkoxides of [omicron]-silyl benzyl alcohols in cleavage reactions: approaches to benzyl and silyl anion equivalents

Author

Hudrlik, Paul F., Arango, Jose O., Hijji, Yousef M., Okoro, Cosmas O., and Hudrlik, Anne M.

Subjects
Alcohols, Chemical reactions -- Analysis, Benzene, Ketones, Hydrogen, Anions, Oxides, Chemical research -- Analysis
Abstract

The alkoxides of o-silyl benzyl alcohols 4 undergo cleavage reactions under mild conditions allowing transfer of a benzyl or silyl group to an electrophile. Reactions 3a [right arrow] 8, and 3c or 4c [right arrow] 11 illustrate their potential as benzyl and silyl anion equivalents. Key words: silyl migration, benzyl anion equivalent, silyl anion equivalent, [beta]-silyl ketone, [gamma]-hydroxysilane.

Published
2000

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