1. The effect of crosslinking on ion transport in nanocellulose-based membranes.
- Author
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Yang, Hongli, Edberg, Jesper, Gueskine, Viktor, Vagin, Mikhail, Say, Mehmet Girayhan, Erlandsson, Johan, Wågberg, Lars, Engquist, Isak, and Berggren, Magnus
- Subjects
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ION transport (Biology) , *BIOLOGICAL transport , *ENERGY harvesting , *WATER purification , *NANOFLUIDICS , *ENERGY conversion , *SURFACE charges - Abstract
Ion selective membranes are at the heart of energy conversion and harvesting, water treatment, and biotechnologies. The currently available membranes are mostly based on expensive and non-biodegradable polymers. Here, we report a cation-selective and low-cost membrane prepared from renewable nanocellulose and 1,2,3,4-butanetetracarboxylic acid which simultaneously serves as crosslinker and source of anionic surface groups. Charge density and structure of the membranes are studied. By using different degrees of crosslinking, simultaneous control over both the nanochannel structure and surface charge concentration is achieved, which in turn determines the resulting ion transport properties. Increasing negative charge concentration via higher crosslinker content, the obtained ion conductivity reaches up to 8 mS/cm (0.1 M KCl). Optimal ion selectivity, also influenced by the solution pH, is achieved at 20 wt% crosslinker addition (with ion conductivity of 1.6 mS/cm). As regular ~1.4 nm nanochannels were formed at this composition, nanofluidic contribution to ion transport is likely. • A renewable, low cost crosslinked nanocellulose membrane was reported. • The crosslinked membranes show excellent ion conductivity and selectivity. • A higher amount of crosslinker results in a greater ion conductivity. • An optimal ionic selectivity obtained at an addition of the crosslinker of 20 wt%. • This nanocellulose membrane is promising for ionic devices and upscaled applications. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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