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In this study, chitosan based microbeads containing Ungeremine, an antimicrobial alkaloid particularly active against Penicillium roqueforti, a filamentous fungus responsible of the bakery products deterioration, were prepared by external gelation by using sodium tripolyphosphate (TPP) as crosslinking agent. The stability of the beads, as well as the loading efficiency of the bioactive molecule, were assessed at different pH and TPP concentrations resulting particularly enhanced at low pH. All the microbeads evidenced antimicrobial activity against Penicillium roqueforti. The release kinetics of Ungeremine was tailored by opportunely modulating pH and TPP concentrations. Morphological analysis evidenced the improvement of the structural crosslinking density of microbeads including Ungeremine and spectroscopic analysis emphasized the active participation of Ungeremine to the crosslinking process occurring between chitosan and TPP. Finally, thermogravimetric analysis confirmed the increasing of free volume in three-dimensional networks and their liability to thermal degradation.

Ulomoides dermestoides (UL) are macroinvertebrates insects belonging to Tenebrionidae Coleopteran family. They were used to hasten, in five days, the biodegradation-mineralization of thermoplastic starch (TPS)-poly(lactic acid) (PLA) films, otherwise biodegradable under composting conditions. After the contact of TPS-PLA film with UL for five days, TPS was metabolized and PLA was hydrolysed, as evidenced by decreasing of hydroxyl and carbonyl group peaks intensity by FTIR spectra, increasing of 13% of PLA crystallinity by DSC thermograms, reduction of PLA and TPS thermal stability by TGA analysis; faecal residues evidenced two glass transition temperature T

In this paper, lemon and fennel wastes were recovered and used as secondary-raw polysaccharide sources. These polysaccharides were exploited as natural plasticizers of sodium alginate (A) based films, in order to improve sodium alginate performances, limited by its fragility, extending its potential application in a cost effective and eco-friendly way. Different green processes, such as maceration (MAC), ultrasound assisted extraction (UAE) and microwave assisted extraction (MAE), were carried out for obtaining high yield of lemon and fennel polysaccharides (LP and FP). Actually, HPAE-PAD and TLC analyses evidenced the presence of xyslose, galactose, glucose and rhamnose monomers and galacturonic acid, typical of polysaccharides like pectin and xyloglucan chains. These findings were confirmed by NMR and FTIR spectroscopic analyses. Moreovers, gel filtration chromatography assessed the high molecular weight of recovered polysaccharides, particularly of FP waste fraction. The extracted polysaccharides were used as eco-friendly and cost-effective plasticizers of sodium alginate films (AFP and ALP). DSC analysis evidenced a significant decreasing of glass transition temperature of the polymer, tensile tests showed an enlightened rising of elongation at break and TGA analysis showed a faster degradation kinetics of AFP and ALP films, as expected in a plasticized system.

In this paper, physico-chemical, mechanical and antimicrobial properties of hydrogels based on alginate/N-succinylchitosan blends crosslinked by calcium or zinc ions containing cellulose microfibers were investigated and discussed. With respect to plain alginate hydrogels, the addition of N-succinylchitosan significantly improved properties such as swelling degree and stability in saline solution. The water vapour transmission rate confirmed that all the hydrogels were able to assure a moist wound environment. Morphological analysis showed a good embedding of fibres within the zinc crosslinked hydrogels. In addition, zinc-crosslinked hydrogels evidenced antimicrobial activity against two common skin pathogenic bacteria, Staphylococcus aureus and Escherichia coli. Cytotoxicity assays proved that the amount of zinc released is slightly over the toxic level. Overall, the characteristics of the zinc-crosslinked hydrogels showed their potential interest as materials for wound dressing.

[EN] The use of a modified poly(Epsilon-caprolactone) (gPCL) to enhance polymer miscibility in films based on ther-moplastic starch (S) and poly(Epsilon-caprolactone) is reported. PCL was functionalized by grafting with maleicanyhdride (MA) and/or glycidyl methacrylate (GMA) by reactive blending in a batch mixer. gPCL basedmaterials were analysed in terms of their grafting degree, structural and thermal properties. Blends basedon starch and PCL (wt. ratio 80:20) with including gPCL (0, 2.5 and 5 wt.%), as a compatibilizer, wereobtained by extrusion and compression moulding, and their structural, thermal, mechanical and bar-rier properties were investigated. Blends containing gPCL evidenced better interfacial adhesion betweenstarch and PCL domains, as deduced from both structural (XRD, FTIR, SEM) and bulk properties (DSC, TGA).Moreover, grafted PCL-based compatibilizers greatly improved functional properties of S-PCL blend films,as pointed out from mechanical performance and higher barrier properties, valuable to meet the foodpackaging requirements., The authors gratefully acknowledge the project MAREA, "Materiali Avanzati per la Ricerca ed il comparto Agroalimentare"-in the frame of National Operative Program (PON 2007-2013) and Ministerio de Economia y Competitividad (Spain) throughout the project AGL2013-42989 for their research financial support. They would like to thank the laboratory of electron microscopy "LaMEST" CNR, in the person of Maria Cristina Del Barone for the kind technical assistance in performing SEM analysis. R. Rodrigo Ortega-Toro thanks the Conselleria de Educacio de la Comunitat Valenciana for the Santiago Grisolia grant (GRISOLIA 2012/001) and to Short-Term Scientific Missions (STSM) from European Cooperation in Science and Technology (COST).