1. Electrospun carboxymethyl cellulose acetate butyrate (CMCAB) nanofiber for high rate lithium-ion battery
- Author
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Feijun Wang, Long Xie, Ziqiang Shao, Mingshan Yang, Yunhua Zhang, Lei Qiu, Shaoyi Lv, and Wenjun Wang
- Subjects
Battery (electricity) ,Materials science ,Polymers and Plastics ,Carbon nanofiber ,Lithium iron phosphate ,Organic Chemistry ,Lithium-ion battery ,Lithium battery ,Electrospinning ,Carboxymethyl cellulose ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,Nanofiber ,Materials Chemistry ,medicine ,Composite material ,medicine.drug - Abstract
Cellulose derivative CMCAB was synthesized, and nanometer fiber composite material was obtained from lithium iron phosphate (LiFePO4, LFP)/CMCAB by electrospinning. Under the protection of inert gas, modified LFP/carbon nanofibers (CNF) nanometer material was obtained by carbonization in 600 °C. IR, TG-DSC, SEM and EDS were performed to characterize their morphologies and structures. LFP/CNF composite materials were assembled into lithium-ion battery and tested their performance. Specific capacity was increased from 147.6 mAh g−1 before modification to 160.8 mAh g−1 after modification for the first discharge at the rate of 2 C. After 200 charge–discharge cycles, when discharge rate was increased from 2 C to 5 C to 10 C, modified battery capacity was reduced from 152.4 mAh g−1 to 127.9 mAh g−1 to 106 mAh g−1. When the ratio was reduced from 10 C to 5 C to 2 C, battery capacity can be quickly approximate to the original level. Cellulose materials that were applied to lithium battery can improve battery performance by electrospinning.
- Published
- 2012