Search

Abstract: A series of boron isomorphously framework-substituted ZSM-5 (B x –Al–ZSM-5, Si/Al=200, B/Al=X) were synthesized and used to selectively transform methanol to propylene (MTP). The catalytic stability can be significantly influenced by B incorporation. In comparison with the conventional ZSM-5, the B1–Al–ZSM-5 catalyst afforded a 7-time-long catalytic life under a space velocity of WHSV 1.8h−1 (700h for B1–Al–ZSM-5 and 100h for ZSM-5, respectively). The enhancement of catalytic stability can be attributed to the increase of weak acid sites on the ZSM-5 catalysts. [Copyright &y& Elsevier]