1. Pulse energy-storage performance and temperature stability of Bi2O3-added BaTiO3 based ceramics.
- Author
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Yan, Guiwei, Sun, Jun, Yan, Juanwen, Deng, Tingyu, Fang, Bijun, Hao, Jigong, Zhang, Shuai, Lu, Xiaolong, Zhao, Xiangyong, and Ding, Jianning
- Subjects
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BARIUM titanate , *SPACE charge , *PHASE space , *POWER density , *PERMITTIVITY , *CERAMICS , *CATIONIC polymers - Abstract
The temperature stability and temperature stability range of barium titanate-based pulse energy-storage ceramics were modified by Bi 2 O 3 tailoring in (Ba 0.98- x Li 0.02 Bi x) (Mg 0·04 Ti 0.96)O 3 (x = 0, 0.025, 0.05, 0.075, 0.1) and (Ba 1.03-1.5 x Li 0.02 Bi x) (Mg 0·04 Ti 0.96)O 3 (x = 0.125, 0.15, 0.2, 0.25) ceramics. Excellent pulse energy-storage performances of ceramic films are achieved via the new dual priority strategy of establishing cationic vacancies and forming a liquid phase. The dielectric constant plateau appears due to the cubic phase and space charges. Outstanding temperature stability, frequency stability and antifatigue performance are obtained in the ceramics, and their variations are all less than 15%. The comprehensive energy-storage properties with dual priority parameters of energy-storage density and efficiency of 3.13 J/cm3 and 91.71%, accompanied by an excellent pulse discharge energy density of 2.48 J/cm3, current density of 1313.23 A/cm2 and power density of 195.26 MW/cm3 are gained at x = 0.1. The perfect pulse energy-storage performances as well as ultrahigh stability are correlated with synergistic effects of multiphase coexistence, cubic phase, liquid-phase sintering, grain size, ceramic resistance, space charges and polar nanoregions. The comprehensive parameters indicate that the (Ba 0·88 Li 0·02 Bi 0.1) (Mg 0·04 Ti 0.96)O 3 ceramics have potential application in high precision fields. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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