Search

Your search keyword '"Fareed Bhasha Sayyed"' showing total 1 results
Start Over Author "Fareed Bhasha Sayyed" Journal chem. commun.
1 results on '"Fareed Bhasha Sayyed"'

1. The crucial roles of MgCl2 as a non-innocent additive in the Ni-catalyzed carboxylation of benzyl halide with CO2

Author

Shigeyoshi Sakaki and Fareed Bhasha Sayyed

Subjects
inorganic chemicals, Chemistry, Metals and Alloys, Halide, General Chemistry, Photochemistry, Medicinal chemistry, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Adduct, Carboxylation, Reagent, Materials Chemistry, Ceramics and Composites
Abstract

Ni-catalyzed carboxylation of the C(sp(3))-Cl bond with CO2 in the presence of MgCl2 was theoretically investigated. MgCl2 plays three crucial roles in stabilization of a Ni(I)-CO2 adduct and acceleration of the CO2 insertion as a non-innocent additive and the one-electron reduction process as one kind of reagent.

Published
2014

Catalog

Books, media, physical & digital resources
See catalog results