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1. Graphitic Carbon Nitride as a Heterogeneous Photocatalyst for the Hydrophosphorylation and Hydrophosphorylative Cyclization Reactions of Terminal Alkyne and Its Derived Enynes.

Author

Hou, Hong, Wang, Jiawei, Chen, Xiaoyun, Han, Ying, Yu, Huaguang, Yan, Chaoguo, Shi, Yaocheng, and Zhu, Shaoqun

Subjects
*RING formation (Chemistry), *NITRIDES, *ENYNES, *PHOTOCATALYSTS, *HETEROGENEOUS catalysts, *VISIBLE spectra, *CARBON
Abstract

Visible‐light mediated hydrophosphorylation and hydrophosphorylative cyclization reactions using heterogeneous graphitic carbon nitride as the photocatalyst were described. The phosphorus atom radical was generated and allows the radical addition and addition/cyclization sequence, efficiently resulting in the final phosphorylated alkenes and cycles formation. Recyclable, nontoxic and low‐cost heterogeneous graphitic carbon nitride as visible light photocatalyst provides a new opportunity for the hydrophosphorylation and hydrophosphorylative cyclization reactions under the present redox‐neutral conditions. [ABSTRACT FROM AUTHOR]

Published
2022
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