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1. Synthesis of digermylene-stabilized linear tetraboronate and boroxine.

Author

Wu, Yile, Liu, Liu, Su, Jue, Yan, Kaili, Zhu, Jun, and Zhao, Yufen

Subjects
*DENSITY functional theory, *ELECTRON-deficient compounds, *BORON, *FUNCTIONAL groups, *COVALENT bonds
Abstract

Two newly discovered linear compounds tetraboronate and boroxine stabilized by digermylene are reported, which feature a B4O5 chain and a B3O3 ring, respectively. DFT calculations reveal that not only can digermylene stabilize the electron-deficient boron centers, but also increase the energies of the LUMOs of the boron moiety. Our results provide a hint for the development of boronate covalent organic frameworks. [ABSTRACT FROM AUTHOR]

Published
2016
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