1. A hybrid linkage mode between T2,2 and T3 selenide clusters.
- Author
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Han, Xiaohui, Xu, Jin, Wang, Zhenqing, Liu, Dan, and Wang, Cheng
- Subjects
- *
SELENIDES , *METAL-organic frameworks , *ZEOLITES , *SEMICONDUCTORS , *ION exchange (Chemistry) , *THERMAL conductivity - Abstract
A multi-level 3D selenide framework in an In3+–Ge4+ system was synthesized. The interconnection between super-supertetrahedral T2,2 and supertetrahedral T3 clusters via their terminal Se2− leads to a previously unknown hybrid T2,2–T3 linkage mode. The synthetic realization of this material represents another new level of complexity and demonstrates the versatility in the construction and property-engineering of cluster-based semiconducting materials. [ABSTRACT FROM AUTHOR]
- Published
- 2015
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