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Your search keyword '"Xie, Ying"' showing total 2 results
Start Over Author "Xie, Ying" Topic functional groups Publication Year Range Last 50 years Journal chemical communications
2 results on '"Xie, Ying"'

1. Rh(iii)-catalyzed chelation-assisted intermolecular carbenoid functionalization of α-imino Csp3–H bonds.

Author

Chen, Xun, Xie, Ying, Xiao, Xinsheng, Li, Guoqiang, Deng, Yuanfu, Jiang, Huanfeng, and Zeng, Wei

Subjects
*CHELATION, *IMINO compounds, *LIGANDS (Chemistry), *HYDROGEN bonding, *FUNCTIONAL groups
Abstract

A Rh(iii)-catalyzed cross-coupling/cyclization cascade of α-imino Csp3–H bonds with donor/acceptor α-acyl diazocarbonyl compounds has been developed. This novel transformation involves ligand-directed Csp3–H bond functionalization with carbenoids under the pyridine-chelation assistance, and offered an efficient access to synthetically versatile polysubstituted N-(2-pyridyl)pyrroles with a broad range of functional group tolerance. [ABSTRACT FROM AUTHOR]

Published
2015
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2. An efficient synthesis of optically active trifluoromethyl aldimines via asymmetric biomimetic transamination.

Author

Liu, Mao, Li, Jing, Xiao, Xiao, Xie, Ying, and Shi, Yian

Subjects
*TRIFLUOROMETHYL compounds synthesis, *ALDIMINES, *AMINATION, *BIOMIMETIC chemicals, *FUNCTIONAL groups
Abstract

This communication describes a chiral base-catalyzed asymmetric [1,3]-proton shift of trifluoromethyl ketimines, giving a wide variety of trifluoromethyl aldimines containing various functional groups with up to 94% ee. [ABSTRACT FROM AUTHOR]

Published
2013
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