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4. Catalysis of photooxidation reactions through transformation between Cu2+ and Cu+ in TiO2–Cu–MOF composites.

Author

Chen, Chunjun, Wu, Tianbin, Yang, Dexin, Zhang, Pei, Liu, Huizhen, Yang, Youdi, Yang, Guanying, and Han, Buxing

Subjects
*PHOTOOXIDATION, *TITANIUM dioxide spectra, *STYRENE, *COUPLING reactions (Chemistry), *METAL-organic frameworks
Abstract

Novel porous TiO2@Cu3(BTC)2 composites, which were synthesized using ionic liquids (ILs) as solvents, exhibited excellent activity for photooxidation of styrene to 4-aryl tetralones and promoting the Glaser coupling reaction with O2 under light irradiation. It was discovered that the transformation between Cu2+ and Cu+ was crucial for enhancing the photocatalytic performance. [ABSTRACT FROM AUTHOR]

Published
2018
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