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Your search keyword '"Zhang, Xiao-bo"' showing total 1 results
Start Over Author "Zhang, Xiao-bo" Topic intermolecular interactions Journal chemical communications
1 results on '"Zhang, Xiao-bo"'

1. Catalytic intermolecular carbon electrophile induced semipinacol rearrangement.

Author

Zhang, Qing-Wei, Zhang, Xiao-Bo, Li, Bao-Sheng, Xiang, Kai, Zhang, Fu-Min, Wang, Shao-Hua, and Tu, Yong-Qiang

Subjects
*ELECTROPHILES, *INTERMOLECULAR interactions, *CARBON, *INTERMOLECULAR forces, *CHEMICAL reactions
Abstract

A catalytic intermolecular carbon electrophile induced semipinacol rearrangement was realized and the asymmetric version was also preliminarily accomplished with 92% and 82% ee. The complex tricyclic system architecture with four continuous stereogenic centers could be achieved from simple starting materials in a single step under mild conditions. [ABSTRACT FROM AUTHOR]

Published
2013
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