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Your search keyword '"Zhong, Min"' showing total 1 results
Start Over Author "Zhong, Min" Topic nuclear magnetic resonance spectroscopy Topic porous materials Journal chemical communications
1 results on '"Zhong, Min"'

1. Guest exchange in a porous cucurbit[6]uril-based metal–organic rotaxane framework probed by NMR and X-ray crystallography.

Author

Wu, Xue-Song, Wang, Xin-Long, Zhu, Fu-Long, Bao, Hong-Fei, Qin, Chao, and Su, Zhong-Min

Subjects
ROTAXANES, POROUS materials, NUCLEAR magnetic resonance spectroscopy
Abstract

The first CB[6]-based 3D porous metal–organic rotaxane framework is constructed by the reaction of CuCl2, terephthalic (H2BDC) and CB[6]-based [2]pseudorotaxanes ([PR44]2+·2[PF6]−) under solvothermal conditions. The structure of MORF-1 is a pillared-layer structure with 5-connected sqp topology, in which the effective free volume is 45.4% of the crystal volume. The guest molecules exchange in a single-crystal-to-single-crystal fashion, which was investigated using NMR spectroscopy and X-ray crystallography. [ABSTRACT FROM AUTHOR]

Published
2018
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