1. A bowl-shaped phosphangulene-protected cubic Cu58 nanocluster.
- Author
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Zhang, Qian, Zheng, Hao, Zhou, Jie, Yang, Jia-Ji, Xu, Kai-Yue, Shen, Lian-Yun, Guan, Zong-Jie, and Yang, Yang
- Subjects
X-ray crystallography ,FULLERENES - Abstract
A bowl-shaped phosphangulene-protected cubic Cu
58 nanocluster has been synthesized. The structure was determined by X-ray crystallography and further analyzed by multiple techniques. The phosphangulenes not only enable ligand substitutions with triphenylphosphines in a cluster-to-cluster transformation way, but also facilitate inter-cluster interactions with fullerenes. These interactions further influence the entirety's photocurrent response and ability to liberate hydrogen when stimulated by light. [ABSTRACT FROM AUTHOR]- Published
- 2024
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