1. Modulating the photocatalytic redox preferences between anatase TiO2{001} and {101} surfaces
- Author
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Hongna Zhang, Chuncheng Chen, Hongwei Ji, Wanhong Ma, Jincai Zhao, and Peng Zhou
- Subjects
Anatase ,Chemistry ,Inorganic chemistry ,Metals and Alloys ,Protonation ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Photochemistry ,01 natural sciences ,Redox ,Catalysis ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Deprotonation ,Materials Chemistry ,Ceramics and Composites ,Photocatalysis ,Surface structure ,0210 nano-technology - Abstract
It is widely believed that anatase TiO2 {001} and {101} surfaces acts as the oxidative and reductive sites in photocatalytic reactions, respectively, which is attributed to their different intrinsic surface structures. However, we demonstrate that the photocatalytic redox preferences of TiO2 {001} and {101} surfaces are determined by the adsorbate-reconstructed surface structure instead of their intrinsic surface structures, which can be modulated by surface protonation/deprotonation.
- Published
- 2017
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