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Start Over Author "Ma, Baiwei" Journal chemical communications
4 results on '"Ma, Baiwei"'

4. Catalytic asymmetric Meerwein–Ponndorf–Verley reduction of glyoxylates induced by a chiral N,N′-dioxide/Y(OTf)3 complex.

Author

Wu, Wangbin, Zou, Sijia, Lin, Lili, Ji, Jie, Zhang, Yuheng, Ma, Baiwei, Liu, Xiaohua, and Feng, Xiaoming

Subjects
MOLECULAR sieves, NITROGEN dioxide analysis
Abstract

An asymmetric Meerwein–Ponndorf–Verley (MPV) reduction of glyoxylates was for the first time accomplished via an N,N′-dioxide/Y(OTf)3 complex with aluminium alkoxide and molecular sieves (MSs) as crucial additives. A variety of optically active α-hydroxyesters were obtained with excellent results. A possible reaction mechanism was proposed based on the experiments. [ABSTRACT FROM AUTHOR]

Published
2017
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