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Single-walled carbon nanotubes (SWCNTs) possess superb properties originating from their unique chiral structures. However, accurately controlling the structure of SWCNTs remains challenging due to the structural similarities of their chiral structures, which hinders their widespread application in various fields, particularly in electronics. In recent years, much effort has been devoted to preparing single chiral SWCNTs by adopting three constructive strategies, including growth condition control for structurally unstable liquid catalysts, employing stable solid catalyst design, and pre-synthesis of carbon seeds with a well-defined shape. This review comprehensively discusses the state-of-the-art developments in these approaches as well as their advantages and disadvantages. Moreover, insights into the key challenges and future directions are provided for acquiring chirally pure SWCNTs. [ABSTRACT FROM AUTHOR]

Applying galvanic replacement reactions (GRRs) to the host chiral nanoparticles (CNPs) is an exclusive method to generate alloy CNPs with mesoporous structures through chirality transfer. However, the GRR-mediated chirality transfer is too inefficient to impose strong optical activities on the alloy mesoporous CNPs (or m-CNPs). Here we dope the host with gold (Au) to significantly enhance the chirality transfer, and additionally employ the Au adhesion layer to increase the production yield (PY) of binary m-CNPs. [ABSTRACT FROM AUTHOR]

Carbon monoxide (CO) plays an important role in signaling in cells, making its use as a therapeutic tool highly intriguing. Reduced burst emissions are important to avoid the cytotoxicity and tissue damage caused by CO. Here, we developed a stable diiron carbonyl [FeFe] hydrogenase agent that enables prolonged CO release activity (half-life of over 9 h) in cells. The integrated analysis allowed the identification of the key intermediate sites and CO accumulations with subcellular resolution. We observed that the [FeFe]A complex was enriched in neurons with S-methyl bond rupture. Furthermore, the [FeFe]A complex efficiently reduced the aggregation of tau proteins (49.3% reduction) and showed superior biocompatibility in nerve cells (∼ 95% survival). [ABSTRACT FROM AUTHOR]

Thermoresponsive spherical assemblies formed by a seleniumcontaining small molecule exhibit lower critical solution temperature (LCST) behavior in aqueous solution, which can be reversibly switched by mild redox treatment. [ABSTRACT FROM AUTHOR]

A novel class of ZnSalens (ZnL1–10) with lipophilic and cationic conjugates as optical probes in single and two-photon fluorescence microscopy images of living cells were prepared, which exhibited chemo- and photostability, low cytotoxicity and high subcellular selectivity. [ABSTRACT FROM AUTHOR]