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Start Over Author "Hitesh J. Sanganee" Journal chemical communications (cambridge, england)
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1. Diastereoselective synthesis of pyrrolidine derivatives via a one-pot nitro-Mannich/hydroamination cascade using base and gold catalysis

Author

Hitesh J. Sanganee, Andrej Ďuriš, Darren J. Dixon, and David M. Barber

Subjects
Pyrrolidines, Stereoisomerism, Catalysis, Pyrrolidine, Mannich Bases, chemistry.chemical_compound, Cascade reaction, Materials Chemistry, Organic chemistry, Amination, Molecular Structure, Chemistry, Metals and Alloys, General Chemistry, Hydrogen-Ion Concentration, Nitro Compounds, humanities, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Cascade, Ceramics and Composites, Nitro, Gold, Hydroamination
Abstract

An efficient one-pot nitro-Mannich/hydroamination cascade reaction for the synthesis of substituted pyrrolidines bearing three stereocentres is reported. Proceeding under the control of a combination of base and gold(I) catalysts, the cascade reaction affords the pyrrolidine products in high yields with good to excellent diastereoselectivities.

Published
2013

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