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Start Over Author "Sebastián A. Testero" Journal chemical communications (cambridge, england)
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1. The non-metathetic role of Grubbs' carbene complexes: from hydrogen-free reduction of α,β-unsaturated alkenes to solid-supported sequential cross-metathesis/reduction

Author

Sebastián A. Testero, Ernesto G. Mata, and Andrés A. Poeylaut-Palena

Subjects
Hydrogen, Molecular Conformation, chemistry.chemical_element, Alkenes, Metathesis, Catalysis, chemistry.chemical_compound, Materials Chemistry, Molecule, Ring-opening metathesis polymerisation, Organic chemistry, Microwaves, Olefin fiber, Molecular Structure, Metals and Alloys, General Chemistry, Combinatorial chemistry, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, chemistry, Ceramics and Composites, Organic synthesis, Carbene, Methane
Abstract

An efficient and high-yielding "hydrogen-free" reduction of α,β-unsaturated alkenes was carried out employing Grubbs' catalyst in a non-metathetic role and Et(3)SiH. Conditions were optimized under microwave irradiation. Application to the solid-phase organic synthesis allows a facile construction of sp(3)-sp(3) carbon bonds through a sequential cross metathesis/olefin reduction.

Published
2010

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