1. Supramolecular networks by imine halogen bonding.
- Author
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Nieland E, Komisarek D, Hohloch S, Wurst K, Vasylyeva V, Weingart O, and Schmidt BM
- Abstract
Halogen bonding of neutral donors using imine groups of porous organic cage compounds as acceptors leads to the formation of halogen-bonded frameworks. We report the use of two different imine cages, in combination with three electron-poor halogen bond donors. Four resulting solid-state structures elucidated by single-crystal X-ray analysis are presented and analysed for the first time by plane-wave DFT calculations and QTAIM-analyses of the entire unit cells, demonstrating the formation of halogen bonds within the networks. The supramolecular frameworks can be obtained either from solution or mechanochemically by liquid-assisted grinding.
- Published
- 2022
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