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1. Regioselective placement of alkanethiolate domains on tetrahedral and octahedral gold nanocrystals.

Author

Wang Y, Zeiri O, Meshi L, Stellacci F, and Weinstock IA

Subjects
Ligands, Solubility, Static Electricity, Stereoisomerism, Surface Properties, Tungsten Compounds chemistry, Water chemistry, Alkanes chemistry, Gold chemistry, Metal Nanoparticles chemistry, Sulfhydryl Compounds chemistry
Abstract

Electrostatically stabilized monolayer shells of metal-oxide cluster anions (polyoxometalates, or POMs) on the surfaces of ca. 8 nm tetrahedral and octahedral gold nanocrystals regioselectively direct water-soluble alkanethiolate ligands to the corners and edges of the gold polyhedra.

Published
2012
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