1. Dual-confinement regulating ternary metal-oxide activity sites derived from Co-MOF for enhanced electrocatalytic activity for glucose oxidation.
- Author
-
Zhang, Jing, Zhuang, Xiaoli, Meng, Wei, Tong, Boran, Liu, Lu, Wang, Yue, and Han, Chao
- Subjects
- *
BIMETALLIC catalysts , *OXIDATION of glucose , *GLUCOSE , *CARBON electrodes , *COPPER , *CATALYTIC activity , *ION exchange (Chemistry) - Abstract
[Display omitted] • Based on a dual-confinement regulation, ternary metal-oxide activity sites derived from Co-MOFwere developed. • By chemical confinement, diverse sites were introduced; Then by spatial confinement , Cu x -O-Ni y -O-Co 3-x-y was obtained. • The Cu x -O-Ni y -O-Co 3-x-y modified glassy carbon electrode showed enhanced electrocatalytic activity for glucose oxidation. Based on a dual-confinement strategy on a cobalt-metal-organic framework (Co-MOF), a series of trimetallic-oxide catalysts of Cu x -O-Ni y -O-Co 3-x-y (x/y = 1/1, 1/3, 1/5 and 1/7) were developed for glucose oxidation. By chemical confinement regulation of ion exchange, diverse metal catalytic sites of Cu2+ and Ni2+ were introduced into Co-MOF, respectively; Then by spatial confinement synthesis of pyrolysis, trimetallic MOF of Cu x Ni y Co 3-x-y -MOF was transformed into trimetallic-oxide of Cu x -O-Ni y -O-Co 3-x-y , which maintained the regular morphology and highly ordered lattice structure of Co-MOF. The Cu x -O-Ni y -O-Co 3-x-y composite modified glassy carbon electrode (Cu x -O-Ni y -O-Co 3-x-y /GCE) exhibited enhanced electrocatalytic activity towards glucose oxidation when compared with Co-MOF/GCE, bimetallic MOFs of CuCo-MOF/GCE and NiCo-MOF/GCE, trimetallic MOF of Cu x Ni y Co 3-x-y -MOF/GCE, as well as monometallic oxide Co 3 O 4 /GCE and bimetallic oxides of CuCo 2 O 4 /GCE and NiCo 2 O 4 /GCE, which was mainly due to the synergistic catalysis of electrocatalytically active Co-O-Cu-O-Ni bridges. With Cu2+/Ni2+ molar ratio of 1/3, Cu x -O-Ni y -O-Co 3-x-y /GCE (x/y = 1/3) displayed excellent sensing behaviours on glucose detection. This work not only designed well-performed electrocatalysts for enhancing catalytic activity towards glucose oxidation, but also provided a new perspective to realize the controlled preparation of high-performance electrocatalysts. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF