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• A simple, large-scale fabrication of cooling paper via pulping and papermaking technology. • The cooling paper is facilely deconstructed and regenerated to architect the secondary cooler. • The cooling paper features a high solar reflectance of 94% and emissivity of 0.95. • The cooling paper shows the sub-ambient temperature drop of 6 ∼ 8.8 °C under directly solar radiation at daytime. Passive radiative cooling materials provide coldness without energy consumption for all-day thermal comfort by reflecting solar irradiation and emitting heat into the 3 K universe. However, the conventional radiative cooling materials involve complex multilayer structures and unsustainable polymers, showing the non-recyclable disadvantage, which induces resource waste and environmental issues. Herein, we reported a low-cost, scalable, and eco-friendly radiative cooling material (namely cooling paper), consisting of the delignified, fibrillated cellulose fibers and nano-sized hydroxyapatite (HA) via the mature pulping and papermaking process. The resulting cooled paper can be recycled, and it can be easily deconstructed to harvest cellulose fibers and HA, individually. The recovered source materials can be reused to prepare secondary products that show comparable performance to the original cooling paper, including a high solar reflectance of ∼94% and an infrared emissivity of ∼0.95 in the atmospheric transparency window. Such cooling paper enables superior cooling performance with the temperature drop of 6 ∼ 8.8 °C under directly solar radiation. Based on the EnergyPlus simulation, our cooling paper shows a average cooling energy saving of ∼29 % in buildings across China. The recyclable cooling paper with high cooling capability and scalability, as well as environmental friendliness, shows promising potential for sustainable energy-efficient buildings. [ABSTRACT FROM AUTHOR]