1. Magnetic recyclable lanthanum-nitrogen co-doped titania/strontium ferrite/diatomite heterojunction composite for enhanced visible-light-driven photocatalytic activity and recyclability.
- Author
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Chen, Yan, Wu, Qiong, Bu, Naishun, Wang, Jun, and Song, Youtao
- Subjects
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STRONTIUM ferrite , *HETEROJUNCTIONS , *DIATOMACEOUS earth , *LANTHANUM compounds , *CHARGE transfer , *VISIBLE spectra - Abstract
• La/N co-doped TiO 2 /SrFe 2 O 4 /diatomite (LN-TSD) composite was prepared. • The visible-light-driven photoactivity of LN-TSD was investigated. • The optimal amount of co-dopant and catalyst dosage were determined. • The charge transfer between TiO 2 and SrFe 2 O 4 improved the photocatalytic activity. • The LN-TSD catalyst showed easy separation and good reusability after 5 recycles. Powdery photocatalyst has long been studied, yet its low reusability in suspension system is the bottleneck which hinders its large-scale application. An alternative method to overcome this drawback is developing magnetic recyclable composite. In this work, we prepared lanthanum-nitrogen co-doped titania/strontium ferrite/diatomite (LN-TSD) ternary composite via sol-gel technology. The as-prepared materials were characterized and analyzed, and the photocatalytic activity was evaluated via the elimination of antibiotic oxytetracycline (OTC) under visible light illumination. Charge transfer happened at the heterojunction interface between TiO 2 and strontium ferrite, and thus improved the photocatalytic efficiency by inhibiting the recombination of charge carriers. The photodegradation rate of OTC was accelerated by the high adsorption ability of substrate diatomite, due to the adsorption and degradation synergistic effect between photocatalytic components and substrate diatomite. The optimal dopant amount and catalyst dosage were determined, and the corresponding LN-TSD sample showed its degradation rate of OTC as 95.5% after 2.5 h. The ternary LN-TSD composite could simply be separated from OTC solution via an external magnet, and the repetition tests indicated that, after 5 turns of repetition, only slightly decrease of degradation rate could be observed (dropped to 94.2%). This composite was promising to be applied in wastewater remediation process, due to its good photocatalytic activity under visible light, as well as its good reusability and stability. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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