1. Ultrafast photophysical properties of dimethyl amino styryl pyridine acetonitrile.
- Author
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Li, Lei, Ma, Chaoqun, Zhou, Huangmei, Gu, Jiao, Zhu, Chun, Zhu, Zhuowei, Gao, Hui, Wu, Hui, Wu, Yamin, Chen, Guoqing, and Zhang, Sanjun
- Subjects
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ABSORPTION spectra , *SOLVATION , *ACETONITRILE , *DIPYRRINS - Abstract
• Ultrafast photo-physical properties of DASPA are studied by the TA spectra. • Simulated results suggest multiple binding locations between DASPA and protons. • TA results indicate a solvation relaxation rather than a state-to-state transition. • An energy model is proposed to demonstrate the relaxation mechanism. The ultrafast photophysical properties of dimethyl amino styryl pyridine acetonitrile (DASPA) were studied by the femtosecond transient absorption spectra (TA). The results show no evidence of state-to-state relaxation. The excited energy is released by the interaction between DASPA and solvent molecules. The solvation relaxation in protic solutions is faster than that in aprotic solutions, which results in a rapid decay of fluorescence. An energy diagram is finally proposed to interpret the relaxation mechanism. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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