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Because of their advantages, including easy tunability of optical and electrical properties by tailoring the molecular structure, flexibility, and compatibility with a low-temperature fabricating process, the use of organic semiconductors (OSCs) as active layers has shown strong competitiveness as candidates for use in next-generation high-sensitivity organic photodetectors (OPDs). Infrared (IR) OPDs that are sensitive to illumination at wavelengths higher than 780 nm have been rapidly developed in recent years driven by potential applications such as remote control, night vision, and imaging as well as biomedical monitoring. In this review, after a brief illustration of the mechanisms, we summarize the recent advances in high-performance IR organic photodiodes (OPDIs) and organic phototransistors (OPTs). We will highlight the state-of-the-art protocols for constructing qualified IR OPDs, including new OSCs with excellent photoelectric properties, optimization of active-layer-fabrication processes, and novel device architectures. Thereafter, we will discuss the IR organic light detector as a platform for integrated applications, such as health monitoring, spectrometric analysis, and electronic eyes. This review aims to provide readers with a deeper understanding of the design of future IR OPDs and IR-OPD-based integrated practices. [ABSTRACT FROM AUTHOR]

Organic semiconductors have received broad attention and research interest due to their unique integration of semiconducting properties with structural tunability, intrinsic flexibiltiy and low cost. In order to meet the requirements of organic electronic devices and their integrated circuits, p-type, n-type and ambipolar organic semiconductors are all necessary. However, due to the limitation in both material synthesis and device fabrication, the development of n-type and ambipolar materials is quite behind that of p-type materials. Recent development in synthetic methods of organic semiconductors greatly enriches the range of n-type and ambipolar materials. Moreover, the newly developed materials with multiple functions also put forward multi-functional device applications, including some emerging research areas. In this review, we give a timely summary on these impressive advances in n-type and ambipolar organic semiconductors with a special focus on their synthesis methods and advanced materials with enhanced properties of charge carrier mobility, integration of high mobility and strong emission and thermoelectric properties. Finally, multi-functional device applications are further demonstrated as an example of these developed n-type and ambipolar materials. [ABSTRACT FROM AUTHOR]

Flexible electronics have attracted considerable attention recently given their potential to revolutionize human lives. High-performance organic crystalline materials (OCMs) are considered strong candidates for next-generation flexible electronics such as displays, image sensors, and artificial skin. They not only have great advantages in terms of flexibility, molecular diversity, low-cost, solution processability, and inherent compatibility with flexible substrates, but also show less grain boundaries with minimal defects, ensuring excellent and uniform electronic characteristics. Meanwhile, OCMs also serve as a powerful tool to probe the intrinsic electronic and mechanical properties of organics and reveal the flexible device physics for further guidance for flexible materials and device design. While the past decades have witnessed huge advances in OCM-based flexible electronics, this review is intended to provide a timely overview of this fascinating field. First, the crystal packing, charge transport, and assembly protocols of OCMs are introduced. State-of-the-art construction strategies for aligned/patterned OCM on/into flexible substrates are then discussed in detail. Following this, advanced OCM-based flexible devices and their potential applications are highlighted. Finally, future directions and opportunities for this field are proposed, in the hope of providing guidance for future research. [ABSTRACT FROM AUTHOR]