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For the first time, a highly enantioselective rhodium-catalyzed arylation of benzoxazinones and quinoxalinones is realized by employing an unsaturated chiral sulfoxide ligand. [ABSTRACT FROM AUTHOR]

Review: [37 refs. [ABSTRACT FROM AUTHOR]

The title reaction provides a new method for the synthesis of α-diaryl acetates such as (III), (V), and (VII) in good yields and with high enantioselectivities. [ABSTRACT FROM AUTHOR]

An abstract of the article "Copper-Catalyzed Aerobic Conversion of the C=O Bond of Ketones to a C=N Bond Using Ammonium Salts as the Nitrogen Source" by Bin Xu and colleagues is presented.

Various diarylmethanes are conveniently and efficiently obtained. [ABSTRACT FROM AUTHOR]

A diagram is presented on the amination of ketones through radical mechanism.

Review: 61 refs. [ABSTRACT FROM AUTHOR]

Nano/micro structured porous Li4Ti5O12 for high rate Li-ion batteries is prepared by mixing EtOH solutions of LiOH and PEG to which H2O and (Bu-O)4Ti is given under stirring in an ice bath followed by hydrothermal treatment of the resulting dispersion (autoclave, 120 °C, 24 h), drying, and calcination in air (500-700 °C, 2 h). [ABSTRACT FROM AUTHOR]

An abstract of the article "Copper-Catalyzed Aerobic Decarboxylative Sulfonylation of Cinnamic Acids with Sodium Sulfinates: Stereospecific Synthesis of (E)-Alkenyl Sulfones" by Q. Jiang and colleagues is presented.

isolation and structure of ranaconidine (I) and N-(chloromethyl)taspine (II) [ABSTRACT FROM AUTHOR]

This is the first asymmetric N-H insertion of α-diazoketones giving α-aminoketones in good yields and with high enantioselectivities. [ABSTRACT FROM AUTHOR]

Chemical formulas showing highly enantioselective S-H bond insertion cooperatively catalyzed by dirhodium complexes and chiral spiro phosphoric acids are presented.

Review: 103 refs. [ABSTRACT FROM AUTHOR]

The synthetic value of the present protocol is demonstrated by preparation of herbicide (X). [ABSTRACT FROM AUTHOR]

This method provides access to Boc-protected β,γ-unsaturated α-amino acid esters with excellent yields and enantioselectivities. [ABSTRACT FROM AUTHOR]

The cascade cross-coupling of benzamides with toluene derivatives serves for the efficient construction of various 3-hydroxyisoindolin-1-ones. [ABSTRACT FROM AUTHOR]

An abstract of the article "Iron-Facilitated Oxidative Radical Decarboxylative Cross-Coupling Between α-Oxocarboxylic Acids and Acrylic Acids: An An Approach to α,Β-Unsaturated Carbonyls" by Q. Jiang and colleagues is presented.

The article presents chemical equations related to the article "PIFA-Mediated Esterification Reaction of Alkynes with Alcohols via Oxidative Cleavage of Carbon Triple Bonds" by Q. Jiang and others, published in the periodical "Journal of Organic Chemistry" in 2014.

The title reaction proceeds through a tandem C-C/C-N bond forming process and a N-N bond cleavage. [ABSTRACT FROM AUTHOR]

The title reaction allows a straightforward and efficient access to a number of biologically important 1,2-dihydrophthalazines. [ABSTRACT FROM AUTHOR]

Compound (III) exhibits a potent anti-metastatic activity at well-tolerated doses in an invasive human brest cancer orthotropic mouse model. [ABSTRACT FROM AUTHOR]

A novel method for the preparation of isoquinolines by a Mn-catalyzed oxidative cyclization of vinyl isocyanides with hydrazines is elaborated. [ABSTRACT FROM AUTHOR]

A wide range of aryl/alkylacetic acid methyl esters is environmentally friendly prepared using DMSO as convenient methyl donor and as solvent and hydrogen peroxide as oxidant. [ABSTRACT FROM AUTHOR]

An abstract of the article "K2S2O8-Mediated Nitration of Alkenes with NaNO2 and 2,2,6,6-Tetramethylpiperidine- 1-oxyl: Stereoselective Synthesis of (E)-Nitroalkenes" by An Zhaois, et al. is presented.

The article presents chemical equations related to article "Kinetic Resolution of 2-Substituted-2,3-dihydrofurans by a Palladium-Catalyzed Asymmetric Heck Reaction" by H. Li, and others published in "Royal Society of Chemistry Advances" in 2015.

The regioselective synthesis of pharmacologically relevant polysubstituted Δ2-isoxazolines is based on the copper-mediated direct transformation of terminal alkynes and alkenes. [ABSTRACT FROM AUTHOR]

The article presents chemical equations related to the article "Rhodium(I)-Catalyzed Asymmetric Carbene Insertion into B-H Bonds: Highly Enantioselective Access to Functionalized Organoboranes" published in the periodical "Journal of the American Chemical Society" in 2015.

A novel protocol for the regioselective synthesis of multisubstituted 4-acyloxy-pyrazoles such as (III) and (V) in a single step from hydrazones and carboxylic acids is reported. [ABSTRACT FROM AUTHOR]

The article presents chemical equations related to the article "Mn(II)/Oxygen-Promoted Oxidative Annulation of Vinyl Isocyanides with Boronic Acids: Synthesis of Multi-Substituted Isoquinolines" by H. Wang and others, published in the periodical "Chemical Communications" in 2014.

Depending of the electronic and steric properties of the substrates mono- or dialkoxycarbonylation is achieved. [ABSTRACT FROM AUTHOR]

The article presents a chemical reaction of azaindoles by using 1,2-dicholoroethane.

The article presents chemical equations related to the article "Hypervalent Iodine(III) Promoted Direct Synthesis of Imidazo[1,2-a]pyrimidines" by G. Qian, B. Liu and others, published in the periodical "European Journal of Organic Chemistry" in 2014.

The article presents chemical equations related to the article "Rhodium-Catalyzed Direct ortho C?N Bond Formation of Aromatic Azo Compounds with Azides" by H. Wang and others, published in the periodical "Journal of Organic Chemistry" in 2014.

The article presents chemical equations related to the article "Rhodium-Catalyzed Direct C-H Bond Cyanation of Arenes with Isocyanide" by X. Hong and others, published in the periodical "Journal of Organic Chemistry" in 2014.

The first Cu-mediated multicomponent reaction proceeding through sequential isocyanide insertion into N-H bond, reductive elimination of CuH and 1,3-acyl transfer is demonstrated. [ABSTRACT FROM AUTHOR]

Si/mesoporous carbon composite is prepared from a mixture of SiO2 powder, Mg powder, and mesoporous carbon heated in a tube furnace at 650 °C for 6 h under Ar. [ABSTRACT FROM AUTHOR]

Related compounds such as (XII) are also available. [ABSTRACT FROM AUTHOR]

The nature of the N-substitution is crucial in controlling the regioselectivity of the cyanation of indoles using tBuNC as ′CN′ source and Cu(tfa)2 as oxidant. [ABSTRACT FROM AUTHOR]

An efficient, very simple, and convenient route to the title compounds (II) and (IV) starts from the easily available aryl- and heteroarylacetamides (I) and (III). [ABSTRACT FROM AUTHOR]